Quinonediimine-Induced Oxidative Coupling of Organomagnesium Reagents

被引：14

作者：

Amaya, Toru ^{[1
]}

Suzuki, Riyo ^{[1
]}

Hirao, Toshikazu ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 03期

关键词：

C-C coupling; electron transfer; Grignard reaction; oxidation; redox chemistry; METAL CATALYTIC-SYSTEM; ARYL GRIGNARD-REAGENTS; DEHYDROGENATIVE OXIDATION; ORGANOMETALLIC COMPOUNDS; ELECTRON-TRANSFER; REDOX; POLYANILINES; MAGNESIUM; RADICALS; EXCHANGE;

D O I：

10.1002/chem.201301993

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N,N-Diphenyl-p-benzoquinonediimine, a redox-active unit of polyaniline, efficiently induced the oxidative homocoupling of various aryl- and vinylmagnesium reagents in suppressing the side reactions, such as 1,2- or 1,4-addition reaction.

引用

页码：653 / 656

页数：4