Quinonediimine-Induced Oxidative Coupling of Organomagnesium Reagents

被引：14
作者：
Amaya, Toru [1 ]
Suzuki, Riyo [1 ]
Hirao, Toshikazu [1 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 03期
关键词：
C-C coupling; electron transfer; Grignard reaction; oxidation; redox chemistry; METAL CATALYTIC-SYSTEM; ARYL GRIGNARD-REAGENTS; DEHYDROGENATIVE OXIDATION; ORGANOMETALLIC COMPOUNDS; ELECTRON-TRANSFER; REDOX; POLYANILINES; MAGNESIUM; RADICALS; EXCHANGE;
D O I：
10.1002/chem.201301993
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
N,N-Diphenyl-p-benzoquinonediimine, a redox-active unit of polyaniline, efficiently induced the oxidative homocoupling of various aryl- and vinylmagnesium reagents in suppressing the side reactions, such as 1,2- or 1,4-addition reaction.
引用
收藏
页码：653 / 656
页数：4
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