Tris(2,2′-bipyridyl-κ2N,N′)copper(II) sulfate 7.5-hydrate

被引：4
|
作者：
Xu, Feng [1 ]
You, Wei [1 ]
Huang, Wei [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
基金：
中国国家自然科学基金;
关键词：
CRYSTAL-STRUCTURE;
D O I：
10.1107/S1600536808043821
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu(C10H8N2)(3)]SO4 center dot 7.5H(2)O, is a six-coordinate copper(II) complex with a slightly elongated octahedral coordination geometry. The pyridyl rings of the three bipyridyl ligands are not coplanar, making dihedral angels of 9.5 (5), 5.2 (4) and 5.8 (5)degrees. In the crystal, several O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen-bonding interactions are observed due to the existance of a large number of water molecules and the sulfate dianions.
引用
收藏
页码：M129 / U191
页数：13
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