Functionalised η6-arene ruthenium complexes

被引：188

作者：

Therrien, Bruno ^{[1
]}

机构：

[1] Univ Neuchatel, Inst Chim, CH-2009 Neuchatel, Switzerland

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 3-4期

基金：

瑞士国家科学基金会;

关键词：

Arene ligands; Bio-organometallic chemistry; Clusters; Catalysis; Ruthenium; Piano-stool; P-C BOND; ASYMMETRIC TRANSFER HYDROGENATION; POLYMER-SUPPORTED CATALYSTS; X-RAY-DIFFRACTION; MOLECULAR-STRUCTURE; ARENE COMPLEXES; (ETA(6)-ETA(1)-C6H5CH2CH2PR2)RU(CH3)(2) R; RADICAL POLYMERIZATION; LIGANDS; CHEMISTRY;

D O I：

10.1016/j.ccr.2008.04.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

eta(6)-Arene ruthenium complexes have been known for more than 30 years, and their chemistry has been extensively studied for Unfunctionalised arenes such as benzene, para-cymene and hexamethylbenzene. However, little is known about eta(6)-arene ruthenium complexes in which the arene ligand is not merely an aromatic hydrocarbon but contains chemical functions as substituents. This review gives an overview of functionalised eta(6)-arene ruthenium complexes, their syntheses and structures, as well as their intrinsic potential ranging from biological applications to applications as nano-materials. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：493 / 519

页数：27

共 142 条

[1] Dicationic ruthenium(II) complexes containing bridged η1:η6-phosphinoarene ligands for the ring-opening metathesis polymerization [J].

Abele, A ;

Wursche, R ;

Klinga, M ;

Rieger, B .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 160 (01) :23-33

[2]

Akiyama R, 2002, ANGEW CHEM INT EDIT, V41, P2602, DOI 10.1002/1521-3773(20020715)41:14<2602::AID-ANIE2602>3.0.CO

[3]

2-3

[4] Dichlorido[1-(3,5-dimethylbenzyl)-3-(2,4,6-tri-methylbenzyl)imidazolidin-2-ylidene]ruthenium(II) [J].

Arslan, Hakan ;

VanDerveer, Don ;

Yasar, Sedat ;

Ozdemir, Ismail ;

Cetinkaya, Bekir .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 :M942-M944

[5] Ferrocenoyl pyridine arene ruthenium complexes with anticancer properties:: Synthesis, structure, electrochemistry, and cytotoxicity [J].

Auzias, Mathieu ;

Therrien, Bruno ;

Suess-Fink, Georg ;

Stepnicka, Petr ;

Ang, Wee Han ;

Dyson, Paul J. .

INORGANIC CHEMISTRY, 2008, 47 (02) :578-583

[6] INTRINSIC DEUTERIUM-ISOTOPE EFFECTS OF DEUTERIATED TERT-BUTYL GROUPS ON THE C-13 NMR-SPECTRA OF AROMATIC-COMPOUNDS [J].

BALZER, HH ;

BERGER, S .

MAGNETIC RESONANCE IN CHEMISTRY, 1990, 28 (05) :437-442

[7] Synthesis of a ruthenium complex of a cyclic trifunctional η6, η1, η1-arene-diphosphine ligand by intramolecular dehydrofluorinative carbon-carbon coupling [J].

Bellabarba, RM ;

Saunders, GC ;

Scott, S .

INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (01) :15-18

[8] ARENE RUTHENIUM(II) COMPLEXES FORMED BY DEHYDROGENATION OF CYCLOHEXADIENES WITH RUTHENIUM(III) TRICHLORIDE [J].

BENNETT, MA ;

SMITH, AK .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (02) :233-241

[9] Recent advances in the chemistry of arene complexes of ruthenium(0) and ruthenium(II) [J].

Bennett, MA .

COORDINATION CHEMISTRY REVIEWS, 1997, 166 :225-254

[10] DOUBLE DEPROTONATION, RING-OPENING AND C-C BOND FORMATION IN A COORDINATED CROWN THIOETHER - FORMATION AND STRUCTURE OF AN ARENERUTHENIUM(II) ETHENETHIOLATE, [RU(SCH=CH2)(ETA-6-C6ME5CH2CH2CH2SCH2CH2S)] [J].

BENNETT, MA ;

GOH, LY ;

WILLIS, AC .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (17) :1180-1182

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