Stimuli-responsive star polymers

被引：72

作者：

Kuckling, Dirk ^{[1
]}

Wycisk, Agnes ^{[1
]}

机构：

[1] Univ Paderborn, Dept Chem, D-33098 Paderborn, Germany

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2013年 / 51卷 / 14期

关键词：

atom transfer radical polymerization; block copolymers; living polymerization; reversible addition fragmentation chain transfer (RAFT); star polymers; stimuli-sensitive polymers; LIVING RADICAL POLYMERIZATION; CHAIN-TRANSFER POLYMERIZATION; PHASE-TRANSITION BEHAVIOR; BETA-CYCLODEXTRIN CORE; BLOCK-COPOLYMERS; RAFT POLYMERIZATION; N-ISOPROPYLACRYLAMIDE; DRUG-DELIVERY; AGGREGATION BEHAVIOR; AQUEOUS-SOLUTION;

D O I：

10.1002/pola.26696

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Stimuli-responsive star polymers gain more and more interest over the last decades due to their unique properties compared to their linear counterparts. The branched structure for instance has influence on the responsive behavior of these polymers. This review offers an overview of stimuli-responsive star polymers generated by different polymerization techniques, e.g. anionic and controlled radical polymerization (CRP). Beside conventional branched homopolymers different other types like block copolymers, miktoarm star copolymers, core crosslinked star polymers (CCS) and comb polymers are also presented. Furthermore their responsive behavior in solution or immobilized on a substrate, and their applications are outlined. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 2980-2994

引用

页码：2980 / 2994

页数：15

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