Na2Ti6O13: a potential anode for grid-storage sodium-ion batteries

被引：192

作者：

Rudola, Ashish ^{[1
]}

Saravanan, Kuppan ^{[1
]}

Devaraj, Sappani ^{[1
]}

Gong, Hao ^{[2
]}

Balaya, Palani ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Mech Engn, Singapore 117576, Singapore

[2] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117576, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 67期

关键词：

HIGH-CAPACITY; LITHIUM INSERTION; RATE CAPABILITY; ENERGY-STORAGE; NA; ELECTROLYTE; LI;

D O I：

10.1039/c3cc44381g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ultra-fast (30C or 2 min) rate capability and impressive long cycle life (>5000 cycles) of Na2Ti6O13 are reported. A stable 2.5 V sodium-ion battery full cell is demonstrated. In addition, the sodium storage mechanism and thermal stability of Na2Ti6O13 are discussed.

引用

页码：7451 / 7453

页数：3

共 19 条

[1] Carbon microspheres obtained from resorcinol-formaldehyde as high-capacity electrodes for sodium-ion batteries [J].

Alcántara, R ;

Lavela, P ;

Ortiz, GF ;

Tirado, JL .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (04) :A222-A225

[2] Carbon black:: a promising electrode material for sodium-ion batteries [J].

Alcántara, R ;

Jiménez-Mateos, JM ;

Lavela, P ;

Tirado, JL .

ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (11) :639-642

[3] Insight into the channel ion distribution and influence on the lithium insertion properties of hexatitanates A2Ti6O13 (A = Na, Li, H) as candidates for anode materials in lithium-ion batteries [J].

Carlos Perez-Flores, Juan ;

Garcia-Alvarado, Flaviano ;

Hoelzel, Markus ;

Sobrados, Isabel ;

Sanz, Jesus ;

Kuhn, Alois .

DALTON TRANSACTIONS, 2012, 41 (48) :14633-14642

[4] ELECTROCHEMICAL INSERTION OF SODIUM INTO CARBON [J].

DOEFF, MM ;

MA, YP ;

VISCO, SJ ;

DEJONGHE, LC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (12) :L169-L170

[5] Reversible lithium insertion into Na2Ti6O13 structure [J].

Dominko, R ;

Baudrin, E ;

Umek, P ;

Arcon, D ;

Gaberscek, M ;

Jamnik, J .

ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (04) :673-677

[6] Electrical Energy Storage for the Grid: A Battery of Choices [J].

Dunn, Bruce ;

Kamath, Haresh ;

Tarascon, Jean-Marie .

SCIENCE, 2011, 334 (6058) :928-935

[7] Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries [J].

Komaba, Shinichi ;

Murata, Wataru ;

Ishikawa, Toru ;

Yabuuchi, Naoaki ;

Ozeki, Tomoaki ;

Nakayama, Tetsuri ;

Ogata, Atsushi ;

Gotoh, Kazuma ;

Fujiwara, Kazuya .

ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (20) :3859-3867

[8] Na-ion batteries, recent advances and present challenges to become low cost energy storage systems [J].

Palomares, Veronica ;

Serras, Paula ;

Villaluenga, Irune ;

Hueso, Karina B. ;

Carretero-Gonzalez, Javier ;

Rojo, Teofilo .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (03) :5884-5901

[9] Synthesis, structure and electrochemical Li insertion behaviour of Li2Ti6O13 with the Na2Ti6O13 tunnel-structure [J].

Perez-Flores, J. C. ;

Kuhn, A. ;

Garcia-Alvarado, F. .

JOURNAL OF POWER SOURCES, 2011, 196 (03) :1378-1385

[10] In search of an optimized electrolyte for Na-ion batteries [J].

Ponrouch, Alexandre ;

Marchante, Elena ;

Courty, Matthieu ;

Tarascon, Jean-Marie ;

Rosa Palacin, M. .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (09) :8572-8583

← 1 2 →