Polycondensation of Boron- and Nitrogen-Codoped Holey Graphene Monoliths from Molecules: Carbocatalysts for Selective Oxidation

被引：208

作者：

Li, Xin-Hao ^{[1
]}

Antonietti, Markus ^{[1
]}

机构：

[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14476 Potsdam, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 17期

关键词：

aerobic oxidation; carbocatalysts; dopants; graphene; porous carbon; METAL-FREE ELECTROCATALYSTS; OXYGEN REDUCTION REACTION; CARBON NITRIDE; GRAPHITE OXIDE; FREE CATALYST; SOLVENT-FREE; EFFICIENT; ACTIVATION; GOLD; DEHYDROGENATION;

D O I：

10.1002/anie.201209320

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple but powerful chemical process - the copolymerization of biomass (glucose) and boric acid as templated by dicyandiamide (see picture) - was used to fabricate high-quality doped graphene monoliths with through-plane nanopores. The holey graphene monoliths had a high surface area and showed excellent performance as metal-free carbocatalysts for selective oxidation. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4572 / 4576

页数：5

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