Aerobic Oxidative Coupling of Arenes and Olefins through a Biomimetic Approach

被引：54

作者：

Babu, Beneesh P. ^{[1
]}

Meng, Xu ^{[1
]}

Backvall, Jan-E. ^{[1
]}

机构：

[1] Stockholm Univ, Dept Organ Chem, Arrhenius Lab, S-10691 Stockholm, Sweden

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 13期

基金：

欧洲研究理事会;

关键词：

aerobic oxidation; biomimetic synthesis; C-H activation; dehydrogenative coupling; palladium; C-H ALKENYLATION; HECK REACTION; PALLADIUM; ACID; ACTIVATION; OXYGEN; BONDS; ARYL; FUNCTIONALIZATION; 1,4-OXIDATION;

D O I：

10.1002/chem.201300100

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Arenes and electron-deficient olefins can be oxidatively coupled through a biomimetic Pd(OAc)2-catalyzed transformation. C-H activation of the arene partner is effected under reaction conditions of low catalyst loading, normal oxygen pressure, and using p-benzoquinone and iron phthalocyanine as electron-transfer mediators (ETMs). By controlling catalyst loading, the reaction can be made selective for either mono- or diarylation. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4140 / 4145

页数：6

共 84 条

[1] Ruthenium-Catalyzed Oxidative C-H Alkenylations of Anilides and Benzamides in Water [J].

Ackermann, Lutz ;

Wang, Lianhui ;

Wolfram, Ratnakancana ;

Lygin, Alexander V. .

ORGANIC LETTERS, 2012, 14 (03) :728-731

[2]

[Anonymous], TETRAHEDRON LETT

[3]

[Anonymous], ANGEW CHEM INT ED

[4]

[Anonymous], 2010, ANGEW CHEM-GER EDIT

[5]

[Anonymous], 2009, ITY ANGEW CHEM INT

[6]

[Anonymous], ANGEW CHEM

[7]

[Anonymous], ANGEW CHEM INT ED

[8]

[Anonymous], ANGEW CHEM INT ED

[9]

[Anonymous], ANGEW CHEM INT ED

[10]

[Anonymous], 2006, ANGEW CHEM

← 1 2 3 4 5 6 7 8 9 →