Nanoparticle-enhanced liquid-phase microextraction

被引:45
作者
Bendicho, Carlos [1 ]
Costas-Mora, Isabel [1 ]
Romero, Vanesa [1 ]
Lavilla, Isela [1 ]
机构
[1] Univ Vigo, Fac Quim, Dept Quim Analit & Alimentaria, Area Quim Analit, Vigo 36310, Spain
关键词
Affinity; Carbon nanotube; Liquid-phase microextraction; Magnetic nanoparticle; Nanomaterials; Nanoparticle; Nanoprobe; Noble metal; Oxide nanoparticle; Quantum dot; SINGLE-DROP MICROEXTRACTION; DUAL MAGNETIC MICROEXTRACTION; CARBON NANOTUBES; MASS-SPECTROMETRY; QUANTUM DOTS; SOLID/LIQUID MICROEXTRACTION; CARBAMATE PESTICIDES; HYDROPHOBIC PROTEINS; SILVER NANOPARTICLES; ELECTROSTATIC PROBES;
D O I
10.1016/j.trac.2015.02.007
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Nanostructured materials play roles in different areas of analytical chemistry. Implementation of nanomaterials in liquid-phase microextraction results in a synergic combination yielding enhanced performance. Some significant examples include: carbon nanotubes for improving extraction efficiency; magnetic nanoparticles for retrieving ionic liquids or organic solvents; metal nanoprobes in a solvent microvolume for desalting and ionization in the analysis of proteins and peptides by matrix-assisted laser desorption/ionization-mass spectrometry; in situ generation of noble-metal nanoprobes for extraction of hydride-forming elements prior to their determination by atomic spectrometry; confinement of fluorescent nanoprobes in a microvolume of organic solvent, thereby integrating separation, preconcentration and analyte recognition within a single step; and, solid-phase extraction involving nanomaterials and liquid-phase microextraction in a sequential way. We provide insight into significant advances involving the joint use of nanomaterials and liquid-phase microextraction. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:78 / 87
页数:10
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