Equimolar CO2 Capture by N-Substituted Amino Acid Salts and Subsequent Conversion

被引：226

作者：

Liu, An-Hua ^{[1
,2
]}

Ma, Ran ^{[1
,2
]}

Song, Chan ^{[3
]}

Yang, Zhen-Zhen ^{[1
,2
]}

Yu, Ao ^{[3
]}

Cai, Yu ^{[3
]}

He, Liang-Nian ^{[1
,2
]}

Zhao, Ya-Nan ^{[1
,2
]}

Yu, Bing ^{[1
,2
]}

Song, Qing-Wen ^{[1
,2
]}

机构：

[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China

[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China

[3] Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 45期

关键词：

amino acids; carbamic acid; carbon dioxide fixation; catalysis; poly(ethylene glycol); CARBON-DIOXIDE CAPTURE; IONIC LIQUIDS; KINETICS; ENERGY; SEQUESTRATION; ALKANOLAMINES; TECHNOLOGIES; SEPARATIONS; DERIVATIVES; ABSORPTION;

D O I：

10.1002/anie.201205362

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Steric bulk controls CO 2 absorption: N-substituted amino acid salts in poly(ethylene glycol) reversibly absorb CO 2 in nearly 1:1 stoichiometry. Carbamic acid is thought to be the absorbed form of CO 2; this was supported by NMR and in situ IR spectroscopy, and DFT calculations. The captured CO 2 could be converted directly into oxazolidinones and thus CO 2 desorption could be sidestepped. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11306 / 11310

页数：5

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