Equimolar CO2 Capture by N-Substituted Amino Acid Salts and Subsequent Conversion

被引：226
|
作者：
Liu, An-Hua [1 ,2 ]
Ma, Ran [1 ,2 ]
Song, Chan [3 ]
Yang, Zhen-Zhen [1 ,2 ]
Yu, Ao [3 ]
Cai, Yu [3 ]
He, Liang-Nian [1 ,2 ]
Zhao, Ya-Nan [1 ,2 ]
Yu, Bing [1 ,2 ]
Song, Qing-Wen [1 ,2 ]
机构：
[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China
[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China
[3] Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 45期
关键词：
amino acids; carbamic acid; carbon dioxide fixation; catalysis; poly(ethylene glycol); CARBON-DIOXIDE CAPTURE; IONIC LIQUIDS; KINETICS; ENERGY; SEQUESTRATION; ALKANOLAMINES; TECHNOLOGIES; SEPARATIONS; DERIVATIVES; ABSORPTION;
D O I：
10.1002/anie.201205362
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Steric bulk controls CO 2 absorption: N-substituted amino acid salts in poly(ethylene glycol) reversibly absorb CO 2 in nearly 1:1 stoichiometry. Carbamic acid is thought to be the absorbed form of CO 2; this was supported by NMR and in situ IR spectroscopy, and DFT calculations. The captured CO 2 could be converted directly into oxazolidinones and thus CO 2 desorption could be sidestepped. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：11306 / 11310
页数：5
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