Study the effect of antioxidants on biological activity and on homopolypropylene; mechanical and physical properties

被引:45
作者
Abd El-Wahab, M. [1 ]
El-Desouky, M. G. [2 ]
机构
[1] Suez Canal Univ, Fac Sci, Ismailia, Egypt
[2] Port Said Univ, Fac Sci, Port Fuad, Egypt
关键词
Polypropylene; Extrusion; Compounding; Plastic anti-oxidants; Molecular docking and polymer degradation; DFT CALCULATIONS; CARBON-DIOXIDE; IRON-OXIDE; ADSORPTION; POLYPROPYLENE; EQUILIBRIUM; SARS-COV-2; INHIBITORS; REMOVAL; DYES;
D O I
10.1016/j.jics.2022.100764
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Exposure of polymers to temperature, atmospheric oxygen, or even light could result in some degradation of the polymer properties and features during processing (application), storage and end use. In hydrocarbon polymers, the polymer tend to free radical formation, eventually resulting in chain damage or crosslinking that leads to degradation. Antioxidants are used to terminate these chain reactions by removing radicals. Antioxidants are used in most hydrocarbon polymers including, polypropylene. a good addiction package must be existed to overcome the effect of degradation and save the polymer shape and characteristics. The practical experiment was carried out on a pure polypropylene (intermediate polypropylene resin without additives) and another practical experiment but with adding several types of additives with a certain concentration and study the behavior of polypropylene in all cases with successive extrusions. On other hand Flexible molecular docking on heme oxy-genase, an important stress protein that is involved in cellular protection, antioxidant and anti-inflammatory activities, justified the antioxidant activity of the isolated compounds. From the binding energy 3114 and 1680 they could consider to be powerful and available antioxidant.
引用
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页数:11
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