Mossbauer and magnetization studies of iron oxide nanocrystals

被引:30
作者
Haggstrom, Lennart [1 ]
Kamali, Saeed [1 ,2 ]
Ericsson, Tore [1 ]
Nordblad, Per [3 ]
Ahniyaz, Anwar [4 ]
Bergstrom, Lennart [4 ]
机构
[1] Uppsala Univ, Dept Phys, S-75121 Uppsala, Sweden
[2] Amirkabir Univ, Nano Res Ctr, Tehran, Iran
[3] Uppsala Univ, Dept Engn Sci, S-75121 Uppsala, Sweden
[4] Stockholm Univ, Dept Phys Inorgan & Struct Chem, S-10691 Stockholm, Sweden
来源
HYPERFINE INTERACTIONS | 2008年 / 183卷 / 1-3期
关键词
Maghemite nanoparticles; Anisotropy energy; Mossbauer spectroscopy; Magnetization;
D O I
10.1007/s10751-008-9750-5
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Monodisperse iron oxide nanocrystals have been produced following non-hydrolytic, thermal decomposition routes. Spherically shaped particles with diameter of 4 and 12 nm and cubic shaped particles with an edge length of 9 nm have been studied. The particles have been shown to consist of mainly maghemite. A reduction of the saturation magnetic hyperfine field is observed for the 4 nm particles as compared to the corresponding bulk value. The anisotropy energy determined from the temperature variation of the magnetic hyperfine field was strongly enhanced for the 4 nm particles.
引用
收藏
页码:49 / 53
页数:5
相关论文
共 12 条
[1]   Preparation of iron oxide nanocrystals by surfactant-free or oleic acid-assisted thermal decomposition of a Fe(III) alkoxide [J].
Ahniyaz, Anwar ;
Seisenbaeva, Gulaim A. ;
Haggstrom, Lennart ;
Kamali, Saeed ;
Kessler, Vadim G. ;
Nordblad, Per ;
Johansson, Christer ;
Bergstrom, Lennart .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2008, 320 (06) :781-787
[2]   VACANCY DISTRIBUTION IN SYNTHETIC SPINELS OF SERIES FE3O4-GAMMA-FE2O3 [J].
ANNERSTE, H ;
HAFNER, SS .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1973, 137 (5-6) :321-340
[3]   MOSSBAUER STUDIES IN AN EXTERNAL-FIELD OF WELL-CRYSTALLIZED AL-MAGHEMITES MADE FROM HEMATITE [J].
BOWEN, LH ;
DEGRAVE, E ;
BRYAN, AM .
HYPERFINE INTERACTIONS, 1994, 94 (1-4) :1977-1982
[4]  
De Grave E., 1989, MOSSBAUER SPECTROSCO, P59
[5]   Estimation of blocking temperatures from ZFC/FC curves [J].
Hansen, MF ;
Morup, S .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 203 :214-216
[6]   Physical limits of hyperthermia using magnetite fine particles [J].
Hergt, R ;
Andra, W ;
d'Ambly, CG ;
Hilger, I ;
Kaiser, WA ;
Richter, U ;
Schmidt, HG .
IEEE TRANSACTIONS ON MAGNETICS, 1998, 34 (05) :3745-3754
[7]   Magnetic properties of magnetic liquids with iron-oxide particles - the influence of anisotropy and interactions [J].
Johansson, C ;
Hanson, M ;
Pedersen, MS ;
Morup, S .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1997, 173 (1-2) :5-14
[9]  
Prene P, 1996, ITAL PHY SO, V50, P485
[10]   Synthesis of monodisperse cobalt nanocrystals and their assembly into magnetic superlattices (invited) [J].
Sun, SH ;
Murray, CB .
JOURNAL OF APPLIED PHYSICS, 1999, 85 (08) :4325-4330