An organic photoelectrode working in the water phase: Visible-light-induced dioxygen evolution by a perylene derivative/cobalt phthalocyanine bilayer

被引：98
|
作者：
Abe, T [1 ]
Nagai, K
Kabutomori, S
Kaneko, M
Tajiri, A
Noritnatsit, T
机构：
[1] Hirosaki Univ, Dept Mat Sci & Technol, Hirosaki, Aomori 0368561, Japan
[2] Osaka Univ, ILE, Suita, Osaka 5650871, Japan
[3] Ibaraki Univ, Fac Sci, Mito, Ibaraki 3108512, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 17期
关键词：
dioxygen evolution; photocatalysis; photoelectrochemistry; phthalocyanines; semiconductors;
D O I：
10.1002/anie.200504454
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Two layers are better than one: The organic bilayer composed of 3,4,9,10-perylenetetracarboxylic acid bisbenzimidazole (PTCBI, an n-type semiconductor) and cobalt phthalocyanine (CoPc, a p-type semiconductor) was found to act as a novel photoanode that is responsive to visible light under 750 nm to induce efficiently the photoelectrochemical splitting of water to evolve dioxygen. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2778 / 2781
页数：4
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