Synthesis and structural characterization of [Mn(sapn)(H2O)2]Br

被引：0
|
作者：
Huang, DG [1 ]
Zhu, HP [1 ]
Chen, CN [1 ]
Chen, F [1 ]
Liu, QT [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2002年 / 21卷 / 01期
关键词：
manganese; crystal structure; salicylideneiminate; schiff base;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of the title compound [Mn(sapn)(H2O)(2)]Br (H(2)sapn = N,N'-bis-(salicylidene)-1,3-diaminopropane) with formula C17H18N2O4MnBr and M-r = 449.18 has been determined by X-ray diffraction. The crystal is triclinic with space group P1, a = 7.777(1), b = 10.459(2), c = 11.96(3)Angstrom, alpha 78.22(1),beta =75.16(8), gamma = 86.80(5)degrees, V = 919(3)Angstrom(3), D-c = 1.631 g/cm(3), F(000) = 456, mu = 2.917 cm(-1) and Z = 2, with R = 0.0428 and wR = 0. 1092 for 2427 reflections (I > 2sigma(I)). Two nitrogen and two oxygen atoms from the sapn group chelate to the Mn-III ion, forming a distorted octahedral geometry together with two coordinated water molecules. A bromide anion exists outside as a counter ion.
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页码：64 / 66
页数：3
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