Catalytic oxidation of amines utilizing binuclear copper(II) complex of 7-azaindole

被引：61

作者：

Minakata, S

Ohshima, Y

Takemiya, A

Ryu, I

Komatsu, M

Ohshiro, Y

机构：

[1] OSAKA UNIV, FAC ENGN, DEPT APPL CHEM, SUITA, OSAKA 565, JAPAN

[2] KINKI UNIV, SCI & TECHNOL RES INST, HIGASHIOSAKA, OSAKA 577, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 04期

关键词：

D O I：

10.1246/cl.1997.311

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of benzylamine with a catalytic amount of a binuclear copper(II) complex of 7-azaindole 1 under an oxygen atmosphere at room temperature produced benzylidene-benzylamine and benzonitrile in good yields. This reaction is also applicable to other amines and gives the corresponding imines. Interestingly 1-phenylpyrrolidine was oxidized to cyclic dimers, but, in the presence of triethylamine, it was oxidized to the corresponding gamma-lactam.

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页码：311 / 312

页数：2

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