Synthesis and Evaluation of TiO2/Chitosan based hydrogel for the Adsorptional Photocatalytic Degradation of Azo and Anthraquinone Dye under UV Light Irradiation

被引:60
|
作者
Dhanya, A. [1 ]
Aparna, K. [1 ]
机构
[1] NIT Calicut, Dept Chem Engn, Calicut 673601, Kerala, India
关键词
TiO2; nanoparticles; Chitosan; Azo dye; Anthraquinone dye; Photocatalytic degradation; TITANIUM-DIOXIDE; TEXTILE EFFLUENT; PHOTOMINERALISATION; PHOTODEGRADATION; 4-CHLOROPHENOL; FUNDAMENTALS;
D O I
10.1016/j.protcy.2016.05.141
中图分类号
TP39 [计算机的应用];
学科分类号
081203 ; 0835 ;
摘要
The high rate of electron/hole pair recombination while using TiO2 as a photocatalyst reduces the quantum yield of the process. Adding a co-adsorbent can increase the photocatalytic efficiency of TiO2. In this study, a composite of TiO2 /Chitosan were synthesised in which chitosan also acts as an immobilization agent. The characterization of TiO2 nanoparticles is done using Scanning Electron Micrograph and energy dispersive x-ray spectroscopy measurements. The experimental results show that TiO2 nanoparticles encapsulated in Chitosan can remove the dyes from wastewater almost entirely. The parameters that affect the degradation process are initial concentration of the dye solution, contact time, catalyst concentration, effect of ions and pH. While using TiO2 in slurry form requires separation of the photocatalyst from the treated solution, while in the immobilization technique, the requirement of separation can be avoided.
引用
收藏
页码:611 / 618
页数:8
相关论文
共 50 条
  • [21] Photocatalytic degradation of azo dye reactive orange 16 by TiO2
    Department of Tourism, Hsing Wu College, Taipei 244, Taiwan
    Water Air Soil Pollut., 2009, 1-4 (335-342):
  • [22] Photocatalytic Degradation of Azo Dye Reactive Orange 16 by TiO2
    Chih-Yu Chen
    Water, Air, and Soil Pollution, 2009, 202 : 335 - 342
  • [23] Photocatalytic degradation of cationic azo dye by TiO2/bentonite nanocomposite
    Sun, ZS
    Chen, YX
    Ke, Q
    Yang, Y
    Yuan, J
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 149 (1-3) : 169 - 174
  • [24] Effects of Au nanoparticles on TiO2 in the photocatalytic degradation of an azo dye
    Marta Mrowetz
    Alberto Villa
    Laura Prati
    Elena Selli
    Gold Bulletin, 2007, 40 : 154 - 160
  • [25] Effects of Au nanoparticles on TiO2 in the photocatalytic degradation of an azo dye
    Mrowetz, Marta
    Villa, Alberto
    Prati, Laura
    Selli, Elena
    GOLD BULLETIN, 2007, 40 (02) : 154 - 160
  • [26] Photocatalytic Degradation of the Azo Dye Acid Red 14 in Nanosized TiO2 Suspension under Simulated Solar Light
    Miao, Jing
    Lu, Hai-Bo
    Habibi, Daryoush
    Khiadani, Mehdi H.
    Zhang, Lai-Chang
    CLEAN-SOIL AIR WATER, 2015, 43 (07) : 1037 - 1043
  • [27] Elucidation of the photocatalytic degradation mechanism of an azo dye under visible light in the presence of cobalt doped TiO2 nanomaterials
    El Mragui, Abderrahim
    Zegaoui, Omar
    Esteves da Silva, Joaquim C. G.
    CHEMOSPHERE, 2021, 266
  • [28] Photocatalytic degradation of gentamicin using TiO2 nanoparticle driven by UV light irradiation
    Singh, Harshulika
    Ahlawat, Amit
    Dhiman, Tarun Kumar
    Solanki, Pratima R.
    MATERIALS LETTERS, 2023, 346
  • [29] Photocatalytic degradation of three azo dyes using immobilized TiO2 nanoparticles on glass plates activated by UV light irradiation: Influence of dye molecular structure
    Khataee, A. R.
    Pons, M. N.
    Zahraa, O.
    JOURNAL OF HAZARDOUS MATERIALS, 2009, 168 (01) : 451 - 457
  • [30] Modification of TiO2 with Ag nanoparticles using gamma irradiation method for photocatalytic degradation of azo dye
    Nhu Vo Thi Thu
    Khoi Dang Dinh
    Journal of the Australian Ceramic Society, 2021, 57 : 1563 - 1570