Synthesis and Evaluation of TiO2/Chitosan based hydrogel for the Adsorptional Photocatalytic Degradation of Azo and Anthraquinone Dye under UV Light Irradiation

被引:61
作者
Dhanya, A. [1 ]
Aparna, K. [1 ]
机构
[1] NIT Calicut, Dept Chem Engn, Calicut 673601, Kerala, India
来源
INTERNATIONAL CONFERENCE ON EMERGING TRENDS IN ENGINEERING, SCIENCE AND TECHNOLOGY (ICETEST - 2015) | 2016年 / 24卷
关键词
TiO2; nanoparticles; Chitosan; Azo dye; Anthraquinone dye; Photocatalytic degradation; TITANIUM-DIOXIDE; TEXTILE EFFLUENT; PHOTOMINERALISATION; PHOTODEGRADATION; 4-CHLOROPHENOL; FUNDAMENTALS;
D O I
10.1016/j.protcy.2016.05.141
中图分类号
TP39 [计算机的应用];
学科分类号
081203 ; 0835 ;
摘要
The high rate of electron/hole pair recombination while using TiO2 as a photocatalyst reduces the quantum yield of the process. Adding a co-adsorbent can increase the photocatalytic efficiency of TiO2. In this study, a composite of TiO2 /Chitosan were synthesised in which chitosan also acts as an immobilization agent. The characterization of TiO2 nanoparticles is done using Scanning Electron Micrograph and energy dispersive x-ray spectroscopy measurements. The experimental results show that TiO2 nanoparticles encapsulated in Chitosan can remove the dyes from wastewater almost entirely. The parameters that affect the degradation process are initial concentration of the dye solution, contact time, catalyst concentration, effect of ions and pH. While using TiO2 in slurry form requires separation of the photocatalyst from the treated solution, while in the immobilization technique, the requirement of separation can be avoided.
引用
收藏
页码:611 / 618
页数:8
相关论文
共 15 条
[1]  
Afarani H. R. E., 2008, World Applied Sciences Journal, V3, P738
[2]   Factors influencing the photocatalytic degradation of Rhodamine B by TiO2-coated non-woven paper [J].
Barka, Noureddine ;
Qourzal, Samir ;
Assabbane, Ali ;
Nounah, Abederrahman ;
Ait-Ichou, Yhya .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2008, 195 (2-3) :346-351
[3]   Chitosan-A versatile semi-synthetic polymer in biomedical applications [J].
Dash, M. ;
Chiellini, F. ;
Ottenbrite, R. M. ;
Chiellini, E. .
PROGRESS IN POLYMER SCIENCE, 2011, 36 (08) :981-1014
[4]   PHOTODEGRADATION OF 2-CHLOROPHENOL AND 3-CHLOROPHENOL IN TIO2 AQUEOUS SUSPENSIONS [J].
DOLIVEIRA, JC ;
ALSAYYED, G ;
PICHAT, P .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1990, 24 (07) :990-996
[5]   Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: A review of fundamentals, progress and problems [J].
Gaya, Umar Ibrahim ;
Abdullah, Abdul Halim .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2008, 9 (01) :1-12
[6]   A review of TiO2 nanoparticles [J].
Gupta, Shipra Mital ;
Tripathi, Manoj .
CHINESE SCIENCE BULLETIN, 2011, 56 (16) :1639-1657
[7]   TiO2 photocatalysis:: A historical overview and future prospects [J].
Hashimoto, K ;
Irie, H ;
Fujishima, A .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2005, 44 (12) :8269-8285
[8]   Photocatalysis fundamentals revisited to avoid several misconceptions [J].
Herrmann, Jean-Marie .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 99 (3-4) :461-468
[9]   Solar photocatalytic treatment of simulated dyestuff effluents [J].
Kositzi, M ;
Antoniadis, A ;
Poulios, I ;
Kiridis, I ;
Malato, S .
SOLAR ENERGY, 2004, 77 (05) :591-600
[10]   PHOTOMINERALISATION OF 4-CHLOROPHENOL SENSITIZED BY TITANIUM-DIOXIDE - A STUDY OF THE INTERMEDIATES [J].
MILLS, A ;
MORRIS, S ;
DAVIES, R .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1993, 70 (02) :183-191