Synthesis of Earth-abundant Cu2SnS3 for Solar Cells

被引:7
作者
Tiwari, D. [1 ]
Chaudhuri, T. K. [1 ]
机构
[1] Charotar Univ Sci & Technol, Dr KC Patel Res & Dev Ctr, Changa 388421, Gujarat, India
来源
SOLID STATE PHYSICS: PROCEEDINGS OF THE 55TH DAE SOLID STATE PHYSICS SYMPOSIUM 2010, PTS A AND B | 2011年 / 1349卷
关键词
Copper tin sulphide; nanopowder; semiconductor; X-ray diffraction; THIN-FILMS;
D O I
10.1063/1.3606342
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Cu2SnS3 (CTS) is an emerging semiconducting absorber layer material for solar cells having energy band gap of around 1 eV. In this work CTS powders has been synthesized from metal salts using different sulphur sources. It is found that thiourea yielded pure CTS. The composition of the prepared material has been confirmed by X-ray diffraction (XRD), which shows the CTS powder to be nanocrystalline with triclinic phase. Also the time of the completion of reaction has been optimized by studying the XRD pattern of the product at different time interval of reaction. The diffuse reflectance spectrum of CTS depicts the energy band gap for the sample to be 1.1 eV. The electrical measurement of the pellet of the CTS powders proves the material to have p-type conduction with thermoelectric coefficient of 95 mu V/K as determined from hot-probe method. The electrical conductivity of the pellet is 10(-2) mho/cm.
引用
收藏
页码:1295 / 1296
页数:2
相关论文
共 5 条
[1]  
Amlouk A., 2010, VACUUM, DOI [10.1016/j.vacuum.20210.04.002, DOI 10.1016/J.VACUUM.20210.04.002]
[2]   Structural and optical properties of Cu2SnS3 sprayed thin films [J].
Bouaziz, M. ;
Amlouk, M. ;
Belgacem, S. .
THIN SOLID FILMS, 2009, 517 (07) :2527-2530
[3]   PHOTOVOLTAIC CHARACTERISTICS OF THIN-FILMS OF CU2SNS3 [J].
KUKU, TA ;
FAKOLUJO, OA .
SOLAR ENERGY MATERIALS, 1987, 16 (1-3) :199-204
[4]   Band-gap determination from diffuse reflectance measurements of semiconductor films, and application to photoelectrochemical water-splitting [J].
Murphy, A. B. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2007, 91 (14) :1326-1337
[5]   High-Efficiency Solar Cell with Earth-Abundant Liquid-Processed Absorber [J].
Todorov, Teodor K. ;
Reuter, Kathleen B. ;
Mitzi, David B. .
ADVANCED MATERIALS, 2010, 22 (20) :E156-+