Synthesis and Crystal Structures of Schiff Base Nickel(II) Complexes With Biological Activity

被引:6
|
作者
Shi, Da-Hua [1 ,2 ]
Cao, Zhi-Ling [1 ]
Liu, Wei-Wei [1 ]
Xu, Rui-Bo [1 ]
Zhang, Na [3 ]
Gao, Liu-Liu [1 ]
Zhang, Qian [1 ]
机构
[1] Huaihai Inst Technol, Sch Chem Engn, Lianyungang 222005, Peoples R China
[2] Huaihai Inst Technol, Jiangsu Key Lab Marine Biotechnol, Lianyungang 222005, Peoples R China
[3] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian, Peoples R China
关键词
crystal structure; nickel; Schiff base; synthesis; urease inhibition; UREASE INHIBITORY-ACTIVITIES; CADMIUM(II) COMPLEXES; COMPARTMENTAL LIGANDS; METAL-COMPLEXES;
D O I
10.1080/15533174.2012.680157
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two mononuclear nickel(II) complexes, [Ni(MMP)(NCS)] (1) and [Ni(PMP)(NCS)] (2), where MMP = 5-methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenolate, PMP = 5-methoxy-2-[(pyridin-2-ylmethylimino)methyl]phenolate, were prepared and structurally characterized by X-ray diffraction. The Ni atom in each complex is four-coordinated by three donor atoms of the Schiff base ligand, and by one thiocyanate N atom, forming a square planar coordination. The urease inhibitory activity of the complexes was evaluated.
引用
收藏
页码:1128 / 1131
页数:4
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