Synthesis of a new class of chiral β-mercaptoalcohols from amino acids

被引:0
|
作者
Ge, JF [1 ]
Shen, ZX [1 ]
Zhang, LF [1 ]
Zhang, YW [1 ]
机构
[1] Suzhou Univ, Dept Chem & Chem Engn, Suzhou 215006, Jiangsu, Peoples R China
关键词
beta-mercaptoalcohols; amino acids; synthesis;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The syntheses of three new optically active beta -mercaptoalcohols, (R)-1,1-diphenyl-2-mercapto-3-methyl-1-butanol, (R)-1,1-diphenyl-2-mercapto-4-methyl-1-pentanol, and (R)-1,1-diphen-2-mercapto-1-benzenepropanol from the corresponding amino adds am described. The enantiomeric excesses of these beta -mercaptoalcohols were determined by H-1 NMR as their (S)-mandeloyl derivatives.
引用
收藏
页码:79 / 84
页数:6
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