A Synthetic Strategy for Two Complexes with 1, 2, 3-Triazole Derivatives: Crystal Structures and Hirshfeld Surface Analysis

被引：1

作者：

Feng Chao ^{[1
]}

Zhang Duo ^{[1
]}

Zhou Shi-Yan ^{[1
]}

Chen Jin-Mei ^{[1
]}

Zuo Ze-Hao ^{[1
]}

Zhao Hong ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 32卷 / 07期

关键词：

1H-1,2,3-triazole acid derivatives; crystal structure; Hirshfeld surface analysis; 2D fingerprint plots; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESES; ZN(II) COMPLEXES;

D O I：

10.11862/CJIC.2016.147

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new complexes [Co(H2O)(6)][Co(L-1)(3)](2)center dot 4H(2)O (1) and Cu(L-2)(2) (2) were synthesized by 1H-1,2,3-triazole acid derivatives under various reaction conditions (HL1=5-methy1-1-pheny1-1H-1,2,3-triazole-4-carboxylic acid; HL2=1-(4-iodophenyl)-5-methyl-1H-1,2,3-triazole-4-carboxylic acid). The crystal structures have been established by single-crystal X-ray diffraction, and characterized by FTIR. Hirshfeld surface analysis for complexes 1 and 2 indicate that the 2D fingerprint plots obviously show the main intermolecular interactions in both complexes. CCDC: 1400174, 1; 1400175, 2.

引用

页码：1215 / 1222

页数：8

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