From metal to ligand electroactivity in nickel(II) oxamato complexes

被引：53

作者：

Ottenwaelder, X

Ruiz-García, R

Blondin, G

Carasco, R

Cano, J

Lexa, D

Journaux, Y

Aukauloo, A

机构：

[1] Univ Paris 11, Chim Inorgan Lab, F-91405 Orsay, France

[2] Lab Bioenerget & Ingn Prot, F-13402 Marseille 20, France

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 05期

关键词：

D O I：

10.1039/b312295f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The locus of oxidation in square-planar nickel(II) oxamato complexes can be continuously shifted from the metal to the ligand by an appropriate choice of electron-donating substituents on the aromatic moiety of the ligand.

引用

页码：504 / 505

页数：2

共 24 条

[11]

2-H

[12] Molecular and electronic structures of bis-(o-diiminobenzosemiquinonato)metal(II) complexes (Ni, Pd, Pt), their monocations and -anions, and of dimeric dications containing weak metal-metal bonds [J].

Herebian, D ;

Bothe, E ;

Neese, F ;

Weyhermüller, T ;

Wieghardt, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (30) :9116-9128

[13] Experimental evidence for the noninnocence of o-aminothiophenolates:: Coordination chemistry of o-iminothionebenzosemiquinonate(1-) π-radicals with Ni(II), Pd(II), Pt(II) [J].

Herebian, D ;

Bothe, E ;

Bill, E ;

Weyhermüller, T ;

Wieghardt, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (41) :10012-10023

[14] SOLUTION PROPERTIES OF BIS(DIPEPTIDE)NICKELATE(III) COMPLEXES AND KINETICS OF THEIR DECOMPOSITION IN ACID [J].

JACOBS, SA ;

MARGERUM, DW .

INORGANIC CHEMISTRY, 1984, 23 (09) :1195-1201

[15]

KAIM W, 1988, COMMENTS INORG CHEM, V7, P269

[16] LOW-POTENTIAL NICKEL(III,II) COMPLEXES - NEW SYSTEMS BASED ON TETRADENTATE AMIDATE THIOLATE LIGANDS AND THE INFLUENCE OF LIGAND STRUCTURE ON POTENTIALS IN RELATION TO THE NICKEL SITE IN [NIFE]-HYDROGENASES [J].

KRUGER, HJ ;

PENG, G ;

HOLM, RH .

INORGANIC CHEMISTRY, 1991, 30 (04) :734-742

[17] Nickel complexes containing catecholate, benzoquinone and semiquinone radical ligands [J].

Lange, CW ;

Pierpont, CG .

INORGANICA CHIMICA ACTA, 1997, 263 (1-2) :219-224

[18] OXIDATION AND REDUCTION BEHAVIOR OF MACROCYCLIC COMPLEXES OF NICKEL - ELECTROCHEMICAL AND ELECTRON-SPIN RESONANCE STUDIES [J].

LOVECCHIO, FV ;

GORE, ES ;

BUSCH, DH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (10) :3109-3118

[19] NICKEL-(II) AND NICKEL-(III) COMPLEXES WITH NIS4 ENVIRONMENTS - ELECTRON-PARAMAGNETIC RESONANCE AND ELECTROCHEMICAL STUDIES [J].

MUKHOPADHYAY, S ;

RAY, D .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (07) :1159-1162

[20] MONO-VALENT, TRIVALENT AND TETRAVALENT NICKEL [J].

NAG, K ;

CHAKRAVORTY, A .

COORDINATION CHEMISTRY REVIEWS, 1980, 33 (02) :87-147

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