From metal to ligand electroactivity in nickel(II) oxamato complexes

被引：53

作者：

Ottenwaelder, X

Ruiz-García, R

Blondin, G

Carasco, R

Cano, J

Lexa, D

Journaux, Y

Aukauloo, A

机构：

[1] Univ Paris 11, Chim Inorgan Lab, F-91405 Orsay, France

[2] Lab Bioenerget & Ingn Prot, F-13402 Marseille 20, France

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 05期

关键词：

D O I：

10.1039/b312295f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The locus of oxidation in square-planar nickel(II) oxamato complexes can be continuously shifted from the metal to the ligand by an appropriate choice of electron-donating substituents on the aromatic moiety of the ligand.

引用

页码：504 / 505

页数：2

共 24 条

[1] Synthesis and structural characterisation of the first homoleptic organometallic nickel(III) compound [J].

Alonso, PJ ;

Falvello, LR ;

Fornies, J ;

Martin, A ;

Menjon, B ;

Rodriguez, G .

CHEMICAL COMMUNICATIONS, 1997, (05) :503-504

[2]

Aukauloo A, 1999, EUR J INORG CHEM, P1067

[3]

BANERJEE R, 2003, CHEM REV, V103

[4] FORMATION OF NICKEL(III) COMPLEXES WITH N-DENTATE AMINE MACROCYCLES (N=4,5,6) - ELECTRON-SPIN-RESONANCE AND ELECTROCHEMICAL STUDIES [J].

BENCINI, A ;

FABBRIZZI, L ;

POGGI, A .

INORGANIC CHEMISTRY, 1981, 20 (08) :2544-2549

[5] Electronic structure of bis(o-iminobenzosemiquinonato)metal complexes (Cu, Ni, Pd).: The art of establishing physical oxidation states in transition-metal complexes containing radical ligands [J].

Chaudhuri, P ;

Verani, CN ;

Bill, E ;

Bothe, E ;

Weyhermüller, T ;

Wieghardt, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (10) :2213-2223

[6] A SQUARE-PLANAR NICKEL(III) COMPLEX OF AN INNOCENT LIGAND SYSTEM [J].

COLLINS, TJ ;

NICHOLS, TR ;

UFFELMAN, ES .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (12) :4708-4709

[7] New metal oxamates as precursors of low-dimensional heterobimetallics [J].

Fettouhi, M ;

Ouahab, L ;

Boukhari, A ;

Cador, O ;

Mathoniere, C ;

Kahn, O .

INORGANIC CHEMISTRY, 1996, 35 (17) :4932-4937

[8] Spectroscopic characterisation of electrogenerated nickel(III) species.: Complexes with N2O2 Schiff-base ligands derived from salicylaldehyde [J].

Freire, C ;

de Castro, B .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (09) :1491-1497

[9] High-valent transition metal centers and noninnocent ligands in metalloporphyrins and related molecules: a broad overview based on quantum chemical calculations [J].

Ghosh, A ;

Steene, E .

JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2001, 6 (07) :739-752

[10]

Gordon-Wylie SW, 1998, CHEM-EUR J, V4, P2173, DOI 10.1002/(SICI)1521-3765(19981102)4:11<2173::AID-CHEM2173>3.3.CO

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