Strong enhancement of the chemiluminescence of the cerium(IV)-thiosulfate reaction by carbon dots, and its application to the sensitive determination of dopamine

被引：66

作者：

Amjadi, Mohammad ^{[1
]}

Manzoori, Jamshid L. ^{[1
]}

Hallaj, Tooba ^{[1
]}

Sorouraddin, Mohammad H. ^{[1
]}

机构：

[1] Univ Tabriz, Dept Analyt Chem, Fac Chem, Tabriz 5166616471, Iran

来源：

MICROCHIMICA ACTA | 2014年 / 181卷 / 5-6期

关键词：

Carbon dots; Chemiluminescence; Dopamine; Cerium; QUANTUM-DOTS; SELECTIVE DETECTION; ACID; NANOPARTICLES; SYSTEM;

D O I：

10.1007/s00604-014-1172-2

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

We show that the very weak chemiluminescence (CL) of the Ce(IV)-thiosulfate system is enhanced by a factor of similar to 150 in the presence of fluorescent carbon dots (C-dots). The C-dots were prepared by a solvothermal method and characterized by fluorescence spectra and transmission electron microscopy. Possible mechanisms that lead to the effect were elucidated by recording fluorescence and CL spectra. It is found that dopamine at even nanomolar levels exerts a diminishing effect on the enhancement of CL. This was exploited to design a method for the determination of dopamine in the concentration range from 2.5 nM to 20 mu M, with a limit of detection (at 3 s) of 1.0 nM. Dopamine was determined by this method in spiked human plasma samples with satisfactory results.

引用

页码：671 / 677

页数：7

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