Key aspects of crystalline Mo-V-O-based catalysts active in the selective oxidation of propane

被引：27
|
作者：
Ueda, Wataru [1 ]
Vitry, Damian [1 ]
Kato, Tomokazu [1 ]
Watanabe, Nobufumi [1 ]
Endo, Yusuke [1 ]
机构：
[1] Hokkaido Univ, Ctr Catalysis Res, Kita Ku, Sapporo, Hokkaido 0010021, Japan
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2006年 / 32卷 / 3-4期
关键词：
selective oxidation; crystalline catalyst; Mo-V-O; alkane; metal oxide catalyst;
D O I：
10.1163/156856706777346435
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mo-V-O-based complex metal oxide catalysts were synthesized hydrothermally for the first time, characterized structurally and tested in the selective oxidation of propane to acrylic acid, and the results obtained were compared on the basis of catalyst crystal structures in order to clarify key aspects of alkane selective oxidation over multifunctional metal oxide catalysts. The catalysts tested were black solids of rod-shaped crystals, which had a layer structure in the direction of fiber axis and various high dimensional arrangements of metal octahedra in the cross-section plane. A strong dependency on the octahedra arrangements and a facet dependency were observed, and the roles of metal elements in the course of selective oxidation of propane were clarified by comparing the catalytic performance of various Mo-V-O-based catalysts. We discuss the multi-functional character derived from high dimensional structures of the catalysts and mechanism of the selective oxidation of propane.
引用
收藏
页码：217 / 233
页数：17
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