Magnetic-Field-Dependent Effect on the Synthesis of Cu2O Crystals

被引:0
作者
Kong, Chuncai [1 ]
Sun, Shaodong [1 ]
Sun, Zhanbo [1 ]
Ding, Bingjun [1 ]
Yang, Zhimao [1 ]
机构
[1] Xi An Jiao Tong Univ, Sch Sci, State Key Lab Mech Behav Mat, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Xian 710049, Shaanxi, Peoples R China
来源
ADVANCED MATERIALS AND INFORMATION TECHNOLOGY PROCESSING II | 2012年 / 586卷
关键词
Cuprous Oxide; magnetic field; synthesis; MICROCRYSTALS; AGGREGATION;
D O I
10.4028/www.scientific.net/AMR.586.121
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effect of magnetic field on the morphology and properties of Cu2O has been investigated by using a high magnetic field (B = 7 T) during the synthesis of Cu2O. Transmission electron microscopy (TEM) images showed that the variation of Cu2O crystal microstructures from nanospheres to nanoparticle-aggregates under the introduction of external magnetic field. And the optical band gap energy (E-g) of Cu2O was changed from 2.51 eV (nanospheres) to 2.27 eV (nanoparticle-aggregates). The effect of high magnetic field on the structure and properties is expected to be widely used to improve various crystals.
引用
收藏
页码:121 / 125
页数:5
相关论文
共 21 条
[1]   Role of magnetic forces in electrochemical reactions at microstructures [J].
Bund, A ;
Kuehnlein, HH .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (42) :19845-19850
[2]   Formation of colloidal CuO nanocrystallites and their spherical aggregation and reductive transformation to hollow CU2O nanospheres [J].
Chang, Y ;
Teo, JJ ;
Zeng, HC .
LANGMUIR, 2005, 21 (03) :1074-1079
[3]   Manipulative synthesis of multipod frameworks for self-organization and self-amplification of Cu2O microcrystals [J].
Chang, Y ;
Zeng, HC .
CRYSTAL GROWTH & DESIGN, 2004, 4 (02) :273-278
[4]   Morphology of magneto-electrodeposited Cu2O microcrystals [J].
Daltin, Anne-Lise ;
Addad, Ahmed ;
Baudart, Patrick ;
Chopart, Jean-Paul .
CRYSTENGCOMM, 2011, 13 (10) :3373-3377
[5]   Microcrystals Electrodeposited in a High Magnetic Field [J].
Daltin, Anne-Lise ;
Chopart, Jean-Paul .
CRYSTAL GROWTH & DESIGN, 2010, 10 (05) :2267-2271
[6]   Magnetic field effects on copper electrolysis [J].
Hinds, G ;
Spada, FE ;
Coey, JMD ;
Mhíocháin, TRN ;
Lyons, MEG .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (39) :9487-9502
[7]   Fabrication of truncated rhombic dodecahedral Cu2O nanocages and nanoframes by particle aggregation and acidic etching [J].
Kuo, Chun-Hong ;
Huang, Michael H. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (38) :12815-12820
[8]   Polyhedral 50-Facet Cu2O Microcrystals Partially Enclosed by {311} High-Index Planes: Synthesis and Enhanced Catalytic CO Oxidation Activity [J].
Leng, Mei ;
Liu, Mingzhu ;
Zhang, Yibo ;
Wang, Zhenqing ;
Yu, Chao ;
Yang, Xiangguang ;
Zhang, Hongjie ;
Wang, Cheng .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (48) :17084-17087
[9]   Magnetic field effects on electrochemical processes: A theoretical hydrodynamic model [J].
Lioubashevski, O ;
Katz, E ;
Willner, I .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (18) :5778-5784
[10]   Nano-sized transition-metaloxides as negative-electrode materials for lithium-ion batteries [J].
Poizot, P ;
Laruelle, S ;
Grugeon, S ;
Dupont, L ;
Tarascon, JM .
NATURE, 2000, 407 (6803) :496-499