Conventional and New Materials for Selective Catalytic Reduction (SCR) of NOx

被引:103
作者
Liu, Yu [1 ]
Zhao, Jun [1 ]
Lee, Jong-Min [1 ]
机构
[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore
关键词
ammonia; deNO(x); low-temperature; metal-organic frame (MOFs); selective catalytic reduction (SCR); METAL-ORGANIC FRAMEWORKS; NITRIC-OXIDE; DIESEL-ENGINE; EFFICIENT CATALYST; NITROGEN-OXIDES; CARBON-DIOXIDE; PHYSICOCHEMICAL PROPERTIES; CHEMICAL DEACTIVATION; NONTHERMAL PLASMA; MIXED OXIDES;
D O I
10.1002/cctc.201701414
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is important and necessary to minimize NOx pollutant released into the atmosphere owing to the harmful environmental and health effects brought by NOx emission. Many techniques are available to reduce NOx emission, among of them, Selective Catalytic Reduction (SCR) is considered as one of the most efficient techniques. Conventional SCR systems involve ammonia (NH3) or urea (CO(NH2)(2)) as a reducing reagent to reduce NOx to N-2 and H2O at high temperatures 300-400 degrees C. Research on developing novel low-temperature catalysts (LTC) for SCR of NOx still remains of interest. This work reviewed and compared conventional SCR catalysts with newly emerging Metal-Organic-Frame (MOFs) materials as potential alternatives for SCR catalysts.
引用
收藏
页码:1499 / 1511
页数:13
相关论文
共 139 条
  • [1] ANATASE CRYSTAL-GROWTH AND PHASE-TRANSFORMATION TO RUTILE IN HIGH-AREA TIO2, MOO3-TIO2 AND OTHER TIO2-SUPPORTED OXIDE CATALYTIC-SYSTEMS
    AMORES, JMG
    ESCRIBANO, VS
    BUSCA, G
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (08) : 1245 - 1249
  • [2] [Anonymous], 2005, ANGEW CHEM
  • [3] [Anonymous], 2016, ATMOSPHERIC CHEM PHY
  • [4] Role of Nitric Oxide Synthases in Parkinson's Disease: A Review on the Antioxidant and Anti-inflammatory Activity of Polyphenols
    Aquilano, Katia
    Baldelli, Sara
    Rotilio, Giuseppe
    Ciriolo, Maria Rosa
    [J]. NEUROCHEMICAL RESEARCH, 2008, 33 (12) : 2416 - 2426
  • [5] NH3 decomposition and oxidation over noble metal-based FCC CO combustion promoters
    Bahrami, Behnam
    Komvokis, Vasileios G.
    Ziebarth, Michael S.
    Alexeev, Oleg S.
    Amiridis, Michael D.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2013, 130 : 25 - 35
  • [6] Control of NOx emissions from diesel engine by selective catalytic reduction (SCR) with urea
    Baik, JH
    Yim, SD
    Nam, IS
    Mok, YS
    Lee, JH
    Cho, BK
    Oh, SH
    [J]. TOPICS IN CATALYSIS, 2004, 30-1 (1-4) : 37 - 41
  • [7] Methods for NH3 titration of Bronsted acid sites in Cu-zeolites that catalyze the selective catalytic reduction of NOx with NH3
    Bates, Shane A.
    Delgass, W. Nicholas
    Ribeiro, Fabio H.
    Miller, Jeffrey T.
    Gounder, Rajamani
    [J]. JOURNAL OF CATALYSIS, 2014, 312 : 26 - 36
  • [8] Correlation between Cu ion migration behaviour and deNOx activity in Cu-SSZ-13 for the standard NH3-SCR reaction
    Beale, A. M.
    Lezcano-Gonzalez, I.
    Slawinksi, W. A.
    Wragg, D. S.
    [J]. CHEMICAL COMMUNICATIONS, 2016, 52 (36) : 6170 - 6173
  • [9] Synthesis and Characterization of Fe-Doped CeO2 for Application in the NO Selective Catalytic Reduction by CO
    Brackmann, Rodrigo
    Toniolo, Fabio Souza
    Schmal, Martin
    [J]. TOPICS IN CATALYSIS, 2016, 59 (19-20) : 1772 - 1786
  • [10] Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites
    Britt, David
    Furukawa, Hiroyasu
    Wang, Bo
    Glover, T. Grant
    Yaghi, Omar M.
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (49) : 20637 - 20640