Chemically Modulated Graphene Diodes

被引:158
作者
Kim, Hye-Young [1 ]
Lee, Kangho [1 ]
McEvoy, Niall [1 ]
Yim, Chanyoung [1 ,2 ]
Duesberg, Georg S. [1 ]
机构
[1] Trinity Coll Dublin, CRANN, Dublin 2, Ireland
[2] Trinity Coll Dublin, Sch Chem, Dublin 2, Ireland
关键词
Graphene Schottky diode; chemical doping of graphene; chemical sensor; ideality factor; Schottky barrier height; GAS; TRANSISTORS; TRANSPORT;
D O I
10.1021/nl400674k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the manufacture of novel graphene diode sensors (GDS), which are composed of monolayer graphene on silicon substrates, allowing exposure to liquids and gases. Parameter changes in the diode can be correlated with charge transfer from various adsorbates. The GDS allows for investigation and tuning of extrinsic doping of graphene with great reliability. The demonstrated recovery and long-term stability qualifies the GDS as a new platform for gas, environmental, and biocompatible sensors.
引用
收藏
页码:2182 / 2188
页数:7
相关论文
共 32 条
[1]   The electronic properties of graphene [J].
Castro Neto, A. H. ;
Guinea, F. ;
Peres, N. M. R. ;
Novoselov, K. S. ;
Geim, A. K. .
REVIEWS OF MODERN PHYSICS, 2009, 81 (01) :109-162
[2]   Oxygen sensors made by monolayer graphene under room temperature [J].
Chen, C. W. ;
Hung, S. C. ;
Yang, M. D. ;
Yeh, C. W. ;
Wu, C. H. ;
Chi, G. C. ;
Ren, F. ;
Pearton, S. J. .
APPLIED PHYSICS LETTERS, 2011, 99 (24)
[3]   Graphene-Silicon Schottky Diodes [J].
Chen, Chun-Chung ;
Aykol, Mehmet ;
Chang, Chia-Chi ;
Levi, A. F. J. ;
Cronin, Stephen B. .
NANO LETTERS, 2011, 11 (05) :1863-1867
[4]   EXTRACTION OF SCHOTTKY DIODE PARAMETERS FROM FORWARD CURRENT-VOLTAGE CHARACTERISTICS [J].
CHEUNG, SK ;
CHEUNG, NW .
APPLIED PHYSICS LETTERS, 1986, 49 (02) :85-87
[5]   Cell Proliferation Tracking Using Graphene Sensor Arrays [J].
Daly, Ronan ;
Kumar, Shishir ;
Lukacs, Gyongyi ;
Lee, Kangho ;
Weidlich, Anne ;
Hegner, Martin ;
Duesberg, Georg S. .
JOURNAL OF SENSORS, 2012, 2012
[6]   Changes in the electronic structure and properties of graphene induced by molecular charge-transfer [J].
Das, Barun ;
Voggu, Rakesh ;
Rout, Chandra Sekhar ;
Rao, C. N. R. .
CHEMICAL COMMUNICATIONS, 2008, (41) :5155-5157
[7]   Doping Single-Layer Graphene with Aromatic Molecules [J].
Dong, Xiaochen ;
Fu, Dongliang ;
Fang, Wenjing ;
Shi, Yumeng ;
Chen, Peng ;
Li, Lain-Jong .
SMALL, 2009, 5 (12) :1422-1426
[8]   Graphene versus carbon nanotubes for chemical sensor and fuel cell applications [J].
Kauffman, Douglas R. ;
Star, Alexander .
ANALYST, 2010, 135 (11) :2790-2797
[9]   Effect of series resistance on the performance of high resistivity silicon Schottky diode [J].
Keffous, A ;
Siad, M ;
Mamma, S ;
Belkacem, Y ;
Chaouch, CL ;
Menari, H ;
Dahmani, A ;
Chergui, W .
APPLIED SURFACE SCIENCE, 2003, 218 (1-4) :336-342
[10]   Graphene-based nitrogen dioxide gas sensors [J].
Ko, G. ;
Kim, H. -Y. ;
Ahn, J. ;
Park, Y. -M. ;
Lee, K. -Y. ;
Kim, J. .
CURRENT APPLIED PHYSICS, 2010, 10 (04) :1002-1004