Nonhydrolytic sol-gel routes to oxides

被引：404
作者：
Vioux, A
机构：
[1] Université Montpellier II, Sciences et Techniques du Languedoc, F 34095 Montpellier Cedex 5, case 007, Place E. Bataillon
来源：
CHEMISTRY OF MATERIALS | 1997年 / 9卷 / 11期
关键词：
D O I：
10.1021/cm970322a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This review surveys the chemistry of various nonhydrolytic sol-gel processes including hydroxylation in nonaqueous systems and aprotic condensation reactions. Some examples of applications in the field of single and multicomponent oxides demonstrate the interest of these approaches as alternatives to the usual hydrolytic routes. More particularly nonhydrolytic methods lead to improved control over the molecular level homogeneity and stoichiometry of multicomponent oxides.
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页码：2292 / 2299
页数：8
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