Rhenium Solubility in Borosilicate Nuclear Waste Glass: Implications for the Processing and Immobilization of Technetium-99

被引：62

作者：

McCloy, John S. ^{[1
]}

Riley, Brian J. ^{[1
]}

Goel, Ashutosh ^{[1
]}

Liezers, Martin ^{[1
]}

Schweiger, Michael J. ^{[1
]}

Rodriguez, Carmen P. ^{[1
]}

Hrma, Pavel ^{[1
]}

Kim, Dong-Sang ^{[1
]}

机构：

[1] Pacific NW Natl Lab, Richland, WA 99352 USA

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 2012年 / 46卷 / 22期

关键词：

VAPOR HYDRATION TESTS; RE BEHAVIOR; TECHNETIUM; CHEMISTRY; VITRIFICATION; MELTS; TC;

D O I：

10.1021/es302734y

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The immobilization of technetium-99 (Tc-99) in a suitable host matrix has proven to be a challenging task for researchers in the nuclear waste community around the world. In this context, the present work reports on the solubility and retention of rhenium, a nonradioactive surrogate for Tc-99, in a sodium borosilicate glass. Glasses containing target Re concentrations from 0 to 10 000 ppm [by mass, added as KReO4 (Re7+)] were synthesized in vacuum-sealed quartz ampules to minimize the loss of Re from volatilization during melting at 1000 degrees C. The rhenium was found as Re7+ in all of the glasses as observed by X-ray absorption near-edge structure. The solubility of Re in borosilicate glasses was determined to be similar to 3000 ppm (by mass) using inductively coupled plasma optical emission spectroscopy. At higher rhenium concentrations, additional rhenium was retained in the glasses as crystalline inclusions of alkali perrhenates detected with X-ray diffraction. Since Tc-99 concentrations in a glass waste form are predicted to be <10 ppm (by mass), these Re results implied that the solubility should not be a limiting factor in processing radioactive wastes, assuming Tc as Tc7+ and similarities between Re7+ and Tc7+ behavior in this glass system.

引用

页码：12616 / 12622

页数：7

共 35 条

[1]

[Anonymous], 2009, C166309 ASTM INT

[2]

[Anonymous], 2004, PNNL14649

[3]

[Anonymous], 2010, VSL10R19201 CATH U A

[4]

[Anonymous], DOEORP200019 CH2M HI