Ruthenocenoporphyrinoids: Conformation Determines Macrocyclic π Conjugation Transmitted Across a d-Electron Metallocene

被引:30
作者
Grocka, Irena [1 ]
Latos-Grazynski, Lechoslaw [1 ]
Stepien, Marcin [1 ]
机构
[1] Univ Wroclaw, Dept Chem, PL-50383 Wroclaw, Poland
关键词
aromaticity; NMR spectroscopy; porphyrinoids; ruthenium; structure elucidation; PORPHYRINOIDS; AROMATICITY;
D O I
10.1002/anie.201208289
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hinges upon Ru: The hingelike flexibility of ruthenocene plays the critical role as a determinant of aromaticity as exemplified by its aromatic synperiplanar and antiaromatic anticlinal(eclipsed) conformers of ruthenocenoporphyrinoids (see figure). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1044 / 1048
页数:5
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