Heteroatom-doped 3D porous carbon architectures for highly stable aqueous zinc metal batteries and non-aqueous lithium metal batteries

被引:140
作者
An, Yongling [1 ]
Tian, Yuan [1 ]
Li, Yuan [1 ]
Wei, Chuanliang [1 ]
Tao, Yuan [1 ]
Liu, Yongpeng [1 ]
Xi, Baojuan [2 ]
Xiong, Shenglin [2 ]
Feng, Jinkui [1 ]
Qian, Yitai [3 ]
机构
[1] Shandong Univ, Sch Mat Sci & Engn, Minist Educ,SDU & Rice Joint Ctr Carbon Nanomat, Key Lab Liquid Solid Struct Evolut & Proc Mat, Jinan 250061, Peoples R China
[2] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
[3] Univ Sci & Technol China, Dept Chem, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
Zn metal anode; Li metal anode; Dendrite-free; 3D carbon; Heteroatom-doped; SOLID-ELECTROLYTE INTERPHASE; ANODE; DEPOSITION; PERFORMANCE; FRAMEWORK; ENERGY; FOAM;
D O I
10.1016/j.cej.2020.125843
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The cycling life of rechargeable metal cells is mainly restricted by dendritic growth of metals. Herein, N/O dual-doped 3D porous carbon architectures are designed on commercial Cu foam current collector (NOCA@CF) from MOF arrays precursors to suppress the dendrite growth of metal anodes. The unique architecture provides integrated merits of good hydrophilicity/lithiophilicity, abundant nuclear sites, high electronic conductivity and robust framework, which can significantly suppress the dendrite growth of both the aqueous zinc metal anode and nonaqueous lithium metal anode. As a result, both aqueous Zn@NOCA@CF parallel to ILiMn2O4 full cells and non-aqueous Li@NOCA@CF parallel to LiNi0.5Mn1.5O4, Li@NOCA@CF parallel to LiNi0.8Co0.1Mn0.1O2 full cells show superior stable electrochemical performance with high rate capability. Moreover, the results may be interesting for researchers on other metal based rechargeable batteries.
引用
收藏
页数:12
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