Heteroatom-doped 3D porous carbon architectures for highly stable aqueous zinc metal batteries and non-aqueous lithium metal batteries

被引:145
作者
An, Yongling [1 ]
Tian, Yuan [1 ]
Li, Yuan [1 ]
Wei, Chuanliang [1 ]
Tao, Yuan [1 ]
Liu, Yongpeng [1 ]
Xi, Baojuan [2 ]
Xiong, Shenglin [2 ]
Feng, Jinkui [1 ]
Qian, Yitai [3 ]
机构
[1] Shandong Univ, Sch Mat Sci & Engn, Minist Educ,SDU & Rice Joint Ctr Carbon Nanomat, Key Lab Liquid Solid Struct Evolut & Proc Mat, Jinan 250061, Peoples R China
[2] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
[3] Univ Sci & Technol China, Dept Chem, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
Zn metal anode; Li metal anode; Dendrite-free; 3D carbon; Heteroatom-doped; SOLID-ELECTROLYTE INTERPHASE; ANODE; DEPOSITION; PERFORMANCE; FRAMEWORK; ENERGY; FOAM;
D O I
10.1016/j.cej.2020.125843
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The cycling life of rechargeable metal cells is mainly restricted by dendritic growth of metals. Herein, N/O dual-doped 3D porous carbon architectures are designed on commercial Cu foam current collector (NOCA@CF) from MOF arrays precursors to suppress the dendrite growth of metal anodes. The unique architecture provides integrated merits of good hydrophilicity/lithiophilicity, abundant nuclear sites, high electronic conductivity and robust framework, which can significantly suppress the dendrite growth of both the aqueous zinc metal anode and nonaqueous lithium metal anode. As a result, both aqueous Zn@NOCA@CF parallel to ILiMn2O4 full cells and non-aqueous Li@NOCA@CF parallel to LiNi0.5Mn1.5O4, Li@NOCA@CF parallel to LiNi0.8Co0.1Mn0.1O2 full cells show superior stable electrochemical performance with high rate capability. Moreover, the results may be interesting for researchers on other metal based rechargeable batteries.
引用
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页数:12
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