Liquid-Liquid Coexistence Curves and Turbidity Measurements of Benzonitrile plus Tridecane in the Critical Region

被引:6
|
作者
Yin, Tianxiang [1 ]
Bai, Yongliang [1 ]
Xie, Jingjing [1 ]
Chen, Zhiyun [1 ]
An, Xueqin [1 ]
Shen, Weiguo [1 ,2 ]
机构
[1] E China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China
[2] Lanzhou Univ, Dept Chem, Lanzhou 730000, Gansu, Peoples R China
基金
中国国家自然科学基金;
关键词
FLUID CRITICALITY; CRITICAL-BEHAVIOR;
D O I
10.1021/je300630u
中图分类号
O414.1 [热力学];
学科分类号
摘要
Liquid-liquid coexistence curves and turbidity measurements for the binary fluid mixture of {benzonitrile + tridecane} were conducted, from which the corresponding critical exponents and critical amplitudes were obtained. It was found that the critical exponents were in accordance with the theoretic predictions and the critical amplitudes supported the well-known two-scale-factor universality. Moreover, the coexistence curve plotted with temperature against mole fraction was found to be well-represented by the formulism proposed by Gutkowski et al. in the frame of the crossover theory, and the asymmetry of its diameter confirmed the complete scaling theory.
引用
收藏
页码:2479 / 2485
页数:7
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