Aromatic carboxylate effect on dimensionality of three bis(benzimidazole)-based cobalt(II) coordination polymers: Syntheses, structures and properties

被引：20
作者：
Zhang, Ju-Wen [1 ]
Gong, Chun-Hua [1 ]
Hou, Li-Li [1 ]
Tian, Ai-Xiang [1 ]
Wang, Xiu-Li [1 ]
机构：
[1] Bohai Univ, Dept Chem, Liaoning Prov Silicon Mat Engn Technol Res Ctr, Jinzhou 121000, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2013年 / 205卷
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; Bis(benzimidazole); Carboxylate; Dimensionality; Property; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; ZN; CD; CD(II);
D O I：
10.1016/j.jssc.2013.07.013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new metal-organic coordination polymers [Co(4-bbc)(2)(bbbm)] (1), [Co(3,5-pdc)(bbbm)] center dot 2H(2)O (2) and [Co(1,4-ndc)(bbbm)] (3) (4-Hbbc=4-bromobenzoic acid, 3,5-H(2)pdc=3,5-pyridinedicarboxylic acid, 1,4-H(2)ndc=1,4-naphthalenedicarboxylic acid and bbbm=1,1-(1,4-butanediyl)bis-1H-benzimidazole) were hydrothermally synthesized and structurally characterized. Polymer 1 is a 1D chain formed by the bbbm ligands and Co-II ions. Polymer 2 exhibits a 2D network with a (3.4.5)(3(2).4.5.6(2).7(4)) topology. Polymer 3 possesses a 3D three-fold interpenetrating framework. The versatile structures of title polymers indicate that the aromatic carboxylates have an important influence on the dimensionality of 1-3. Moreover, the thermal stability, electrochemical and luminescent properties of 1-3 were investigated. (c) 2013 Elsevier Inc. All rights reserved.
引用
收藏
页码：104 / 109
页数：6
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