Aromatic carboxylate effect on dimensionality of three bis(benzimidazole)-based cobalt(II) coordination polymers: Syntheses, structures and properties

被引：20

作者：

Zhang, Ju-Wen ^{[1
]}

Gong, Chun-Hua ^{[1
]}

Hou, Li-Li ^{[1
]}

Tian, Ai-Xiang ^{[1
]}

Wang, Xiu-Li ^{[1
]}

机构：

[1] Bohai Univ, Dept Chem, Liaoning Prov Silicon Mat Engn Technol Res Ctr, Jinzhou 121000, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2013年 / 205卷

基金：

中国国家自然科学基金;

关键词：

Coordination polymer; Bis(benzimidazole); Carboxylate; Dimensionality; Property; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; ZN; CD; CD(II);

D O I：

10.1016/j.jssc.2013.07.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new metal-organic coordination polymers [Co(4-bbc)(2)(bbbm)] (1), [Co(3,5-pdc)(bbbm)] center dot 2H(2)O (2) and [Co(1,4-ndc)(bbbm)] (3) (4-Hbbc=4-bromobenzoic acid, 3,5-H(2)pdc=3,5-pyridinedicarboxylic acid, 1,4-H(2)ndc=1,4-naphthalenedicarboxylic acid and bbbm=1,1-(1,4-butanediyl)bis-1H-benzimidazole) were hydrothermally synthesized and structurally characterized. Polymer 1 is a 1D chain formed by the bbbm ligands and Co-II ions. Polymer 2 exhibits a 2D network with a (3.4.5)(3(2).4.5.6(2).7(4)) topology. Polymer 3 possesses a 3D three-fold interpenetrating framework. The versatile structures of title polymers indicate that the aromatic carboxylates have an important influence on the dimensionality of 1-3. Moreover, the thermal stability, electrochemical and luminescent properties of 1-3 were investigated. (c) 2013 Elsevier Inc. All rights reserved.

引用

页码：104 / 109

页数：6

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