Synthesis and crystal structure of trans-[Ru(NO)(NH3)4SO4]ClO4 and [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4aEuro¢H2O

被引：1
|
作者：
Makhinya, A. N. [1 ,2 ]
Il'in, M. A. [1 ,2 ]
Baidina, I. A. [1 ]
Korol'kov, I. V. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] Novosibirsk Natl Res State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 57卷 / 06期
关键词：
ruthenium; nitroso complexes; ammino complexes; sulfato complexes; chloro complexes; synthesis; single crystal X-ray diffraction analysis; IR spectroscopy; LINKAGE ISOMERS; COMPLEXES; RUTHENIUM; SPECTRA; STATES;
D O I：
10.1134/S0022476616060184
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
After the addition of the saturated NaClO4 solution to a solution of trans-[Ru(NO)(NH3)(4)SO4]HSO(4)aEuro cent H2O, trans-[Ru(NO)(NH3)(4)SO4]ClO4 perchlorate salt (I) is obtained with the yield of similar to 80%. The heating of trans-[Ru(NO)(NH3)(4)(H2O)](HSO4)SO4 at a temperature of similar to 220 A degrees C results in a complete removal of coordination water and a partial removal of ammonia molecules. Successive treatment of the thermolysis product with sulfuric and hydrochloric acids yields [Ru(NO)(NH3)(4)SO4][Ru(NO)(NH3)(3)Cl(SO4)]HSO(4)aEuro cent H2O crystals (II). The single crystal X-ray diffraction method is used to determine the structure of the compounds obtained. For I: space group P2(1)/c, a = 6.6949(9) , b = 13.7049(19) , c = 12.8641(17) , beta = 101.028(4)A degrees; for II: space group D 2(1)/c, a = 14.1304(4) , b = 12.4908(3) ,, c = 11.6264(3) , beta = 94.1980(10)A degrees.
引用
收藏
页码：1182 / 1187
页数：6
相关论文
共 50 条
  • [1] Synthesis and crystal structure of trans-[Ru(NO)(NH3)4SO4]ClO4 and [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4•H2O
    A. N. Makhinya
    M. A. Il’in
    I. A. Baidina
    I. V. Korol’kov
    Journal of Structural Chemistry, 2016, 57 : 1182 - 1187
  • [2] STRUCTURE OF THE FIRST NITROSOAMMINE COMPLEXES OF RUTHENIUM WITH A COORDINATED SULFATE ION: [Ru(NO)(NH3)4(SO4)](HSO4)•H2O AND [Ru(NO)(NH3)3Cl(SO4)]•2H2O
    Makhinya, A. N.
    Shusharina, E. A.
    Baidina, I. A.
    Il'in, M. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (05) : 946 - 953
  • [3] Structure, synthesis, and thermal properties of trans-[Ru(NO)(NH3)4(SO4)]NO3•H2O
    Makhinya, A. N.
    Il'in, M. A.
    Baidina, I. A.
    Plyusnin, P. E.
    Alferova, N. I.
    Pishchur, D. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (02) : 311 - 318
  • [4] Structure, synthesis, and thermal properties of trans-[Ru(NO)(NH3)4(SO4)]NO3·H2O
    A. N. Makhinya
    M. A. Il’in
    I. A. Baidina
    P. E. Plyusnin
    N. I. Alferova
    D. P. Pishchur
    Journal of Structural Chemistry, 2014, 55 : 311 - 318
  • [5] Structure of the first nitrosoammine complexes of ruthenium with a coordinated sulfate ion: [Ru(NO)(NH3)4(SO 4)](HSO4)·H2O and [Ru(NO)(NH 3)3Cl(SO4)]·2H2O
    Makhinya A.N.
    Shusharina E.A.
    Baidina I.A.
    Il'in M.A.
    Journal of Structural Chemistry, 2011, 52 (5) : 946 - 953
  • [6] Synthesis and crystal structure of trans-nitrosoaquatetraammineruthenium(II) sulphate hydrosulphate, [Ru(NO) (NH3)4(H2O)](SO4)( HSO4)
    Emel'yanov, VA
    Virovets, AV
    Baidina, IA
    Gromilov, SA
    Belyaev, AV
    INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (01) : 33 - 35
  • [7] 是[Cu（NH3）4]SO4还是[Cu（NH3）4]（OH）2?
    蒋树源
    化学教育, 1987, (05) : 53 - 55
  • [8] ISONICOTINAMIDE AS ENTERING LIGAND ON TRANS-[RU(NH3)4P(OME)3(H2O)]2+, TRANS-[RU(NH3)4P(OPR)3(H2O)]2+, TRANS-[RU(NH3)4P(OIPR)3(H2O)]2+, TRANS-[RU(NH3)4P (OBU)3(H2O)]2+
    DONASCIMENTO, JC
    FRANCO, DW
    INORGANICA CHIMICA ACTA, 1986, 113 (01) : 55 - 60
  • [9] ELECTRONIC, INFRARED, AND RESONANCE-RAMAN SPECTROSCOPIC STUDIES OF THE LINEAR-CHAIN, HALOGEN-BRIDGED, MIXED-VALENCE COMPLEXES [PT(NH3)4][PT(NH3)4BR2]HSO4(4), [PT(NH3)4][PT(NH3)4I2]HSO4(4), [PT(NH3)4][PT(NH3)4BR2]CLO4(4), [PT(NH3)4][PT(NH3)4I2]CLO4(4), [PT(NH3)4][PT(NH3)4BR2]BF4(4), [PT(NH3)4][PT(NH3)4I2]BF4(4) - THE X-RAY CRYSTAL-STRUCTURES OF [PT(NH3)4][PT(NH3)4BR2][HSO4]4 AND [PT(NH3)4][PT(NH3)4I2][HSO4]3[OH].H2O(4
    CLARK, RJH
    KURMOO, M
    GALAS, AMR
    HURSTHOUSE, MB
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (12): : 2505 - 2513
  • [10] Crystal structure and properties of [OsO2(NH3)4]SO4 · H2O
    J. N. Burvikova
    I. V. Lin’ko
    N. U. Venskovskiy
    V. B. Rybakov
    Crystallography Reports, 2007, 52 : 221 - 225
12345