Synthesis and crystal structure of trans-[Ru(NO)(NH3)4SO4]ClO4 and [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4aEuro¢H2O

被引：1
作者：
Makhinya, A. N. [1 ,2 ]
Il'in, M. A. [1 ,2 ]
Baidina, I. A. [1 ]
Korol'kov, I. V. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] Novosibirsk Natl Res State Univ, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 57卷 / 06期
关键词：
ruthenium; nitroso complexes; ammino complexes; sulfato complexes; chloro complexes; synthesis; single crystal X-ray diffraction analysis; IR spectroscopy; LINKAGE ISOMERS; COMPLEXES; RUTHENIUM; SPECTRA; STATES;
D O I：
10.1134/S0022476616060184
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
After the addition of the saturated NaClO4 solution to a solution of trans-[Ru(NO)(NH3)(4)SO4]HSO(4)aEuro cent H2O, trans-[Ru(NO)(NH3)(4)SO4]ClO4 perchlorate salt (I) is obtained with the yield of similar to 80%. The heating of trans-[Ru(NO)(NH3)(4)(H2O)](HSO4)SO4 at a temperature of similar to 220 A degrees C results in a complete removal of coordination water and a partial removal of ammonia molecules. Successive treatment of the thermolysis product with sulfuric and hydrochloric acids yields [Ru(NO)(NH3)(4)SO4][Ru(NO)(NH3)(3)Cl(SO4)]HSO(4)aEuro cent H2O crystals (II). The single crystal X-ray diffraction method is used to determine the structure of the compounds obtained. For I: space group P2(1)/c, a = 6.6949(9) , b = 13.7049(19) , c = 12.8641(17) , beta = 101.028(4)A degrees; for II: space group D 2(1)/c, a = 14.1304(4) , b = 12.4908(3) ,, c = 11.6264(3) , beta = 94.1980(10)A degrees.
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页码：1182 / 1187
页数：6
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