Influence of Carbon Deposition on the Hydrogen Distribution in Pd Nanoparticles and Their Reactivity in Olefin Hydrogenation

被引：159

作者：

Wilde, Markus ^{[1
]}

Fukutani, Katsuyuki ^{[1
]}

Ludwig, Wiebke ^{[2
]}

Brandt, Bjoern ^{[2
]}

Fischer, Jan-Henrik ^{[2
]}

Schauermann, Swetlana ^{[2
]}

Freund, Hans-Joachim ^{[2
]}

机构：

[1] Univ Tokyo, Inst Ind Sci, Meguro Ku, Tokyo 1538505, Japan

[2] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 48期

关键词：

butene; depth profile analysis; hydrogenation; nuclear reaction analysis;

D O I：

10.1002/anie.200801923

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanism of olefin hydrogenation on a supported noble-metal catalyst requires the presence of weakly bound hydrogen atoms absorbed in the volume of the metal particle (see picture). Co-adsorbed carbonaceous deposits affect the hydrogen distribution in the metal clusters and critically control their activity and selectivity in olefin conversions. (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9289 / 9293

页数：5

共 20 条

[1] Metal deposits on well-ordered oxide films [J].