Photocatalytic hydrogen evolution based on mercaptopropionic acid stabilized CdS and CdTeS quantum dots

被引:24
|
作者
Baslak, Canon [1 ,2 ]
Aslan, Emre [1 ]
Patir, Imren Hatay [1 ]
Kus, Mahmut [2 ,3 ]
Ersoz, Mustafa [1 ,2 ]
机构
[1] Selcuk Univ, Fac Sci, Chem, TR-42100 Campus Konya, Turkey
[2] Selcuk Univ, Adv Technol Res & Applicat Ctr, Chem, TR-42100 Campus Konya, Turkey
[3] Selcuk Univ, Fac Engn, Chem Engn, TR-42100 Campus Konya, Turkey
关键词
Photocatalytic hydrogen evolution; Quantum dots; IN-SITU; WATER; H-2; NANOCRYSTALS; GENERATION; EFFICIENCY; REDUCTION; CATALYSIS; HYBRID; SALTS;
D O I
10.1016/j.ijhydene.2016.09.168
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photocatalytic hydrogen evolution based on 3-mercaptopropionic acid stabilized CdS, CdTe, and CdTe0.3S0.5 alloyed quantum dots (QDs) have been investigated under visible light irradiation in the aqueous solution by using ascorbic acid solution as a sacrificial electron donor and CoCl2 center dot 6H(2)O as a co-catalyst. CdS and CdTeS alloyed QDs exhibits higher hydrogen evolution rates of 9.3 mmol g(-1), h(-1) and 8 mmol g(-1) h(-1), respectively, which is about two fold higher than CdTe. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:20523 / 20528
页数:6
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