Zinc(II) Complexes with Tetrafluoroterephthalic and Octafluorobiphenyl-4,4-dicarboxylic Acid Anions and 1,10-Phenanthroline

被引：7

作者：

Larionov, S. V. ^{[1
,2
]}

Rakhmanova, M. I. ^{[1
]}

Glinskaya, L. A. ^{[1
]}

Naumov, D. Yu. ^{[1
,2
]}

Vinogradov, A. S. ^{[3
]}

Karpov, V. M. ^{[3
]}

Platonov, V. E. ^{[3
]}

Fadeeva, V. P. ^{[2
,3
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Pr Akad Lavrenteva 3, Novosibirsk 630090, Russia

[2] Novosibirsk Natl Res State Univ, Ul Pirogova 1, Novosibirsk 630090, Russia

[3] Russian Acad Sci, Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Pr Akad Lavrenteva 9, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2019年 / 89卷 / 02期

关键词：

perfluorocarboxylic acids; zinc complexes; photoluminescence; 1; 10-phenanthroline; coordination polymers; PHOTOLUMINESCENT COMPOUNDS; COORDINATION POLYMERS; CRYSTAL-STRUCTURE;

D O I：

10.1134/S1070363219020154

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc(II) complexes with 1,10-phenanthroline and tetrafluoroterephthalate and octafluorobiphenyl 4,4-dicarboxylate anions have been synthesized. According to the IR spectral data, the complexation involves coordination of the metal ion to the nitrogen atoms of phenanthroline and carboxylate oxygen atom of the acid anion. The complexes show photoluminescence in the visible region of the spectrum. The structure of the complex salt [Zn(H2O)(6)][Zn(H2O)(4)(L-2)(2)] H2O, where L-2 is octafluorobiphenyl-4,4-dicarboxylate anion (monodentate ligand), has been determined by X-ray analysis.

引用

页码：261 / 265

页数：5

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