Gold- or platinum-catalyzed tandem cycloisomerization/Prins-type cyclization reactions

被引：133

作者：

Barluenga, J ^{[1
]}

Diéguez, A ^{[1
]}

Fernández, A ^{[1
]}

Rodríguez, F ^{[1
]}

Fañanás, FJ ^{[1
]}

机构：

[1] Univ Oviedo, CSIC, Unidad Asociada, Inst Quim Organomet Enr Moles, E-33006 Oviedo, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 13期

关键词：

carbocycles; domino reactions; gold; homogeneous catalysis; platinum;

D O I：

10.1002/anie.200503874

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Straightforward and efficient: Functionalized eight-membered carbocycles are easily obtained from simple allyl-substituted 5-hexyn-1-ol derivatives by a catalytic tandem sequence involving a 6-exo cycloisomerization followed by a Prins-type cyclization (see scheme). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2091 / 2093

页数：3

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