Chemoselective hydrogenation of α,β-unsaturated aldehydes with modified Pd/C catalyst

被引：9

作者：

Du, Wen Qiang ^{[1
]}

Rong, Ze Ming ^{[1
]}

Liang, Yan ^{[1
]}

Wang, Yong ^{[1
]}

Lu, Xin Yi ^{[1
]}

Wang, Yi Fan ^{[1
]}

Lu, Lian Hai ^{[1
]}

机构：

[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2012年 / 23卷 / 07期

基金：

国家高技术研究发展计划(863计划);

关键词：

Pd/C catalyst; alpha; beta-Unsaturated aldehydes; Hydrogenation; Selectivity; SELECTIVE HYDROGENATION; CINNAMALDEHYDE; HYDROCINNAMALDEHYDE; NANOPARTICLES;

D O I：

10.1016/j.cclet.2012.05.002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective hydrogenation of alpha,beta-unsaturated aldehydes with modified Pd/C catalyst was developed. The reduction of C=O bond could be efficiently inhibited by the addition of carbonates, and high selectivity to the corresponding saturated aldehydes was achieved under mild conditions. This protocol provides an alternative for efficient preparation of saturated aldehydes. (C) 2012 Ze Ming Rong. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

引用

页码：773 / 776

页数：4

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