Ru(II)-catalyzed amidation reactions of 8-methylquinolines with azides via C(sp3)-H activation

被引：52
|
作者：
Liu, Bingxian [1 ]
Li, Bin [1 ]
Wang, Baiquan [1 ,2 ,3 ]
机构：
[1] Nankai Univ, Coll Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China
[3] Chinese Acad Sci, State Key Lab Organomet Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 91期
基金：
中国国家自然科学基金;
关键词：
C-H BOND; DIRECT ORTHO ARYLATION; INTERMOLECULAR AMIDATION; OXIDATIVE FUNCTIONALIZATION; DIRECT AMINATION; SULFONYL AZIDES; ACYL AZIDES; ARENES; SP(2); ARYL;
D O I：
10.1039/c5cc06230f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ru(II)-catalyzed amidation reactions of 8-methylquinolines with azides have been developed. They are the first examples of [(p-cymene)RuCl2](2)-catalyzed C(sp(3))-H bond intermolecular amidation reactions which give quinolin-8-ylmethanamines under mild reaction conditions in good yields.
引用
收藏
页码：16334 / 16337
页数：4
相关论文
共 50 条
  • [1] Rhodium(III)-Catalyzed Alkenylation Reactions of 8-Methylquinolines with Alkynes by C(sp3)-H Activation
    Liu, Bingxian
    Zhou, Tao
    Li, Bin
    Xu, Shansheng
    Song, Haibin
    Wang, Baiquan
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (16) : 4191 - 4195
  • [2] Rhodium(III)-catalyzed C(sp3)-H Amidation of 8-Methylquinolines with Amides at Room Temperature
    Huang, Xiaolei
    You, Jingsong
    CHEMISTRY LETTERS, 2015, 44 (12) : 1685 - 1687
  • [3] Regioselective C(sp3)-H amidation of 8-methylquinolines with N-hydroxyphthalimides
    Kumar, Rohit
    Parmar, Diksha
    Chandra, Devesh
    Sarthi
    Sharma, Upendra
    CHEMICAL COMMUNICATIONS, 2022, 58 (94) : 13151 - 13154
  • [4] Rh(III)-Catalyzed C(sp3)-H Acetoxylation of 8-Methylquinolines
    Chen, You-Ke
    Kang, Yan-Shang
    Xu, Hua-Jin
    Zhang, Ping
    Zhao, Jing
    Li, Tiantian
    Sun, Wei-Yin
    Lu, Yi
    ORGANIC LETTERS, 2020, 22 (14) : 5390 - 5395
  • [5] Ru(II)/Rh(III)-Catalyzed C(sp3)-C(sp3) Bond Formation through C(sp3)-H Activation: Selective Linear Alkylation of 8-Methylquinolines and Ketoximes with Olefins
    Kumar, Rohit
    Kumar, Rakesh
    Parmar, Diksha
    Gupta, Shiv Shankar
    Sharma, Upendra
    JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (02) : 1181 - 1192
  • [6] C(sp3)-H Bond Functionalization of 8-Methylquinolines
    Parmar, Diksha
    Kumar, Rohit
    Sharma, Upendra
    CHEMISTRY-AN ASIAN JOURNAL, 2025, 20 (05)
  • [7] Rhodium(III)-Catalyzed C(sp3)-H Alkylation of 8-Methylquinolines with Maleimides
    Han, Sangil
    Park, Jihye
    Kim, Saegun
    Lee, Suk Hun
    Sharma, Satyasheel
    Mishra, Neeraj Kumar
    Jung, Young Hoon
    Kim, In Su
    ORGANIC LETTERS, 2016, 18 (18) : 4666 - 4669
  • [8] Cp*Rh(III)-Catalyzed Regioselective C(sp3)-H Electrophilic Trifluoromethylthiolation of 8-Methylquinolines
    Sumit
    Chandra, Devesh
    Thakur, Ankita
    Dhiman, Ankit Kumar
    Sharma, Upendra
    JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (19) : 13754 - 13761
  • [9] Cp*Rh(III)-catalyzed C(sp3)-H alkenylation and arylation of 8-methylquinolines with quinones and thiophenes
    Shan, Baode
    Miao, Qing
    Wang, Rui
    Jia, Guohui
    Zhao, Huaiqing
    CATALYSIS COMMUNICATIONS, 2019, 128
  • [10] Palladium catalyzed C(sp3)-H alkylation of 8-methylquinolines with aziridines: access to functionalized γ-quinolinylpropylamines
    Sahoo, Anita
    Paul, Tripti
    Basak, Shubhajit
    Punniyamurthy, Tharmalingam
    CHEMICAL COMMUNICATIONS, 2024, 60 (99) : 14818 - 14821
12345