Ru(II)-catalyzed amidation reactions of 8-methylquinolines with azides via C(sp3)-H activation

被引：52
作者：
Liu, Bingxian [1 ]
Li, Bin [1 ]
Wang, Baiquan [1 ,2 ,3 ]
机构：
[1] Nankai Univ, Coll Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300071, Peoples R China
[3] Chinese Acad Sci, State Key Lab Organomet Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 91期
基金：
中国国家自然科学基金;
关键词：
C-H BOND; DIRECT ORTHO ARYLATION; INTERMOLECULAR AMIDATION; OXIDATIVE FUNCTIONALIZATION; DIRECT AMINATION; SULFONYL AZIDES; ACYL AZIDES; ARENES; SP(2); ARYL;
D O I：
10.1039/c5cc06230f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ru(II)-catalyzed amidation reactions of 8-methylquinolines with azides have been developed. They are the first examples of [(p-cymene)RuCl2](2)-catalyzed C(sp(3))-H bond intermolecular amidation reactions which give quinolin-8-ylmethanamines under mild reaction conditions in good yields.
引用
收藏
页码：16334 / 16337
页数：4
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