Platelet growth of mercuric iodide

被引:3
作者
McGregor, Douglas S. [1 ]
Ariesanti, Elsa [2 ]
机构
[1] Kansas State Univ, Dept Mech & Nucl Engn, SMART Lab, Manhattan, KS 66506 USA
[2] Radiat Monitoring Devices, Watertown, MA 02472 USA
关键词
Growth from vapor; Semiconducting mercury compounds; FRISCH COLLAR DETECTORS; HGI2; FABRICATION; POLYMORPHS; PROGRAM;
D O I
10.1016/j.jcrysgro.2013.03.001
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The Faile growth method, when used with purified mercuric iodide (HgI2), along with low molecular weight polyethylene, has yielded tetragonal prismatic HgI2 crystals. Thermal desorption-gas chromatography/mass spectroscopy (TD-GC/MS) studies reveal the existence of alkanes and ketones in the growth ampoules along with low molecular weight polyethylene, presumably decomposition byproducts from, or impurities in, the polyethylene. The influence of these desorbed byproducts on the HgI2 crystal morphology is compared to the basic Bravais-Friedel-Donnay-Harker (BFDH) crystal model. From these comparisons, it is apparent that ketones assert the most influence on the HgI2 crystal morphology by slowing the growth of the {110} faces, thereby, causing the tetragonal prismatic crystal shapes to grow. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:7 / 15
页数:9
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