Oxide Heterostructures for Efficient Solar Cells

被引:112
作者
Assmann, Elias [1 ]
Blaha, Peter [2 ]
Laskowski, Robert [2 ]
Held, Karsten [1 ]
Okamoto, Satoshi [3 ]
Sangiovanni, Giorgio [1 ,4 ]
机构
[1] Vienna Univ Technol, Inst Solid State Phys, A-1040 Vienna, Austria
[2] Vienna Univ Technol, Inst Mat Chem, A-1040 Vienna, Austria
[3] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA
[4] Univ Wurzburg, Inst Theoret Phys & Astrophys, D-97074 Wurzburg, Germany
关键词
INTERFACE; SUPERLATTICES; TEMPERATURE; INSULATOR;
D O I
10.1103/PhysRevLett.110.078701
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We propose an unexplored class of absorbing materials for high-efficiency solar cells: heterostructures of transition-metal oxides. In particular, LaVO3 grown on SrTiO3 has a direct band gap similar to 1.1 eV in the optimal range as well as an internal potential gradient, which can greatly help to separate the photo-generated electron-hole pairs. Furthermore, oxide heterostructures afford the flexibility to combine LaVO3 with other materials such as LaFeO3 in order to achieve even higher efficiencies with band-gap graded solar cells. We use density-functional theory to demonstrate these features. DOI: 10.1103/PhysRevLett.110.078701
引用
收藏
页数:5
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