Design principles for nonequilibrium self-assembly

被引：74

作者：

Nguyen, Michael ^{[1
,2
]}

Vaikuntanathan, Suriyanarayanan ^{[1
,2
]}

机构：

[1] Univ Chicago, Dept Chem, 5735 S Ellis Ave, Chicago, IL 60637 USA

[2] Univ Chicago, James Franck Inst, 5640 S Ellis Ave, Chicago, IL 60637 USA

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2016年 / 113卷 / 50期

关键词：

self-assembly; nonequilibrium self-assembly; pattern formation; stochastic thermodynamics; second law of thermodynamics; EQUILIBRIUM; NUMBER; SHAPE;

D O I：

10.1073/pnas.1609983113

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

We consider an important class of self-assembly problems, and using the formalism of stochastic thermodynamics, we derive a set of design principles for growing controlled assemblies far from equilibrium. The design principles constrain the set of configurations that can be obtained under nonequilibrium conditions. Our central result provides intuition for how equilibrium self-assembly landscapes are modified under finite nonequilibrium drive.

引用

页码：14231 / 14236

页数：6

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