Bottom-up synthesis of iron and nitrogen dual-doped porous carbon nanosheets for efficient oxygen reduction

被引:26
作者
Du, Peng [1 ,2 ,3 ]
Ma, Fei-Xiang [1 ,2 ,3 ,4 ]
Lyu, Fucong [1 ,3 ,4 ]
He, Kangqiang [2 ]
Li, Zebiao [1 ,2 ,3 ]
Lu, Jian [2 ,3 ,4 ,5 ]
Li, Yang Yang [1 ,2 ,3 ,4 ]
机构
[1] City Univ Hong Kong, Ctr Super Diamond & Adv Films COSDAF, Kowloon, Hong Kong, Peoples R China
[2] City Univ Hong Kong, Dept Mat Sci & Engn, Kowloon, Hong Kong, Peoples R China
[3] City Univ Hong Kong, Hong Kong Branch, Natl Precious Met Mat Engn Res Ctr, Kowloon, Hong Kong, Peoples R China
[4] City Univ Hong Kong, Dept Mech Engn, Kowloon, Hong Kong, Peoples R China
[5] City Univ Hong Kong, Shenzhen Res Inst, Ctr Adv Struct Mat, Shenzhen, Peoples R China
关键词
ELECTROCATALYTIC ACTIVITY; FE; ORR; CATALYSTS; PERFORMANCE; FRAMEWORKS; PYROLYSIS;
D O I
10.1039/c9cc02615k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Iron and nitrogen co-doped porous carbon nanosheets (Fe, N-PCNs) with a small thickness, smooth surface and high specific surface area are fabricated by a facile bottom-up approach as highly efficient noble metal-free catalysts for the oxygen reduction reaction (ORR). The Fe, N-PCN catalyst exhibits a positive half-wave potential (E1/ 2) (0.87 V vs. RHE), a similar four-electron pathway in 0.1 M KOH medium, and an excellent long-term stability.
引用
收藏
页码:5789 / 5792
页数:4
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