Supramolecular Velcro for Reversible Underwater Adhesion

被引：305
作者：
Ahn, Youngjoo [1 ,2 ]
Jang, Yoonjung [1 ,2 ]
Selvapalam, Narayanan [1 ,2 ]
Yun, Gyeongwon [1 ,2 ]
Kim, Kimoon [1 ,2 ]
机构：
[1] Pohang Univ Sci & Technol, Ctr Self Assembly & Complex, Inst Basic Sci, Pohang 790784, South Korea
[2] Pohang Univ Sci & Technol, Ctr Smart Supramol, Dept Chem, Pohang 790784, South Korea
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 11期
关键词：
cucurbiturils; host-guest systems; multivalency; supramolecular chemistry; underwater adhesion; POLYMER MIMICS; CROSS-LINKING; HOST; COMPLEXATION; STABILITY; CHEMISTRY; AFFINITY;
D O I：
10.1002/anie.201209382
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Sticky job: Excellent underwater adhesion with remarkable mechanical and chemical reversibility has been demonstrated with a supramolecular velcro using host-guest chemistry and multivalent interactions (see scheme). Silicon surfaces (blue) functionalized with cucurbit[7]uril (CB[7]) hosts and aminomethylferrocene (Fc) guests adhere under water because of their extraordinarily high affinity. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：3140 / 3144
页数：5
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