A high-performance and well-dispersed Ag-Pd/UCNTs catalyst for aqueous-phase dechlorination of chlorobenzene

被引：8

作者：

Hu, Guanqi ^{[1
]}

Lai, Shiqin ^{[1
]}

Ye, Cui ^{[1
,2
]}

Li, Aiqing ^{[2
]}

Liu, Jianyu ^{[1
]}

Lai, Xuandi ^{[1
,2
]}

Yu, Xuecheng ^{[1
]}

Chen, Xiuli ^{[1
]}

Fu, Hongli ^{[1
]}

Hu, Jianqiang ^{[1
]}

机构：

[1] S China Univ Technol, Coll Chem & Chem Engn, Dept Appl Chem, Key Lab Fuel Cell Technol Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China

[2] Southern Med Univ, Nanfang Hosp, Minist Educ China, Key Lab Organ Failure Res, Guangzhou 510515, Guangdong, Peoples R China

来源：

MATERIALS LETTERS | 2013年 / 93卷

基金：

中国国家自然科学基金;

关键词：

Ag-Pd; Nanomaterials; Unzipping carbon nanotubes; Catalysts; One-pot synthesis; Dechlorination reaction of chlorobezene; CARBON NANOTUBES; GRAPHENE NANORIBBONS; REDUCTION; NANOCUBES;

D O I：

10.1016/j.matlet.2012.11.060

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A facile one-pot strategy to prepare hollow Ag-Pd nanocubes is demonstrated via galvanic replacement reaction of Ag nanocubes, using which a high-performance and well-dispersed Ag-Pd/unzipped carbon nanotubes (Ag-Pd/UCNTs) catalyst for aqueous-phase dechlorination reaction of chlorobenzene is acquired through coupling UCNTs. The structure, size, morphology, and catalytic properties of the Ag-Pd/UCNTs catalyst were characterized by TEM, XRD, and GC-MS. Our results indicate that, besides component, size, and shape of the Pd-based catalysts, supporting materials (e.g., carbon materials) also play an important role in catalytic properties of the Pd-based catalysts. Compared with the pure Ag-Pd nanocubes, Ag-Pd/CNTs, and Ag-Pd/reduced UCNTs (Ag-Pd/RUCNTs), the Ag-Pd/UCNTs catalyst possesses excellent catalytic properties on dechlorination reaction of chlorobenzene. The Ag-Pd/UCNTs catalyst is therefore hopeful to have potential applications in the degradation of aryl halide contaminants. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：278 / 281

页数：4

共 15 条

[1] Solution-phase synthesis of metal and/or semiconductor homojunction/heterojunction nanomaterials [J].